Reaction of the iridacyclopentadiene TpMe2ir(C(R)=C(R)C(R)=C(R)) (H2O) (R = CO2Me) with alkynes

Organometallics

Volumn 28, Issue 1, 2009, Pages 172-180

  Paneque, Margarita ^a   Poveda, Manuel L ^a   Rendón, Nuria ^a   Mereiter, Kurt ^b  

^a INSTITUTO DE INVESTIGACIONES QUÍMICAS   (Spain)

^b VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; HYDROGEN; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; SILICON CARBIDE; X RAY DIFFRACTION ANALYSIS;

ALKENYL; COMPLEX 1; CYCLOPENTADIENE; HYDROGEN ATOMS; IR AND NMR SPECTROSCOPIES; REACTION CONDITIONS; TERMINAL ALKYNES;

IRIDIUM;

EID: 61849103409     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om8001153     Document Type: Article

References (34)

1. (a) Kircnner, R.; Calhorda, M. J.: Scnmid, K.; veiros, L. k j. Am. Chem. Soc. 2003, 125, 11721.
2. (b) Yamamoto, Y.; Arakawa, T.; Ogawa, R.; Itoh, K. J. Am. Chem. Soc. 2003, 125, 12143.
3. (a) Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA. 1987.
4. (b) Kezuka, S.; Tanaka, S.; Ohe, T.; Nakaya, Y.; Takeuchi, R. J. Org. Chem. 2006, 71, 543.
5. (c) Saito, S.; Yamamoto, Y. Chem. Rev. 2000, 100, 2901.
6. (d) Grotjahn, D. B. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 12, Chapter 7.3.
7. (e) Cadierno, V.; García-Garrido, S. E.; Gimeno, J. J. Am. Chem. Soc. 2006, 128, 15094.
8. (f) Kakeya, M.; Fujihara, T.; Kasaya, T.; Nagasawa, A. Organometallics 2006, 25, 4131, and reference.
9. Paneque, M.; Posadas, C. M.; Poveda, M. L.; Rendón, N.; Santos, L. L; Álvarez, E.; Salazar, V.; Mereiter, K.; Oñate, E. Organometallics 2007, 26, 3403.
10. Álvarez, E.; Paneque, M.; Posadas, C. M.; Poveda, M. L.; Rendb́n, N.; Mereiter, K. Chem.-Eur. J. 2007, 13, 5160.
11. Paneque, M.; Poveda, M. L.; Rendón, N.; Mereiter, K. J. Am. Chem. Soc. 2004, 126, 1610.
12. Ilg, K.; Paneque, M.; Poveda, M. L.; Rendón, N.; Santos, L. L.; Carmona, E.; Mereiter, K. Organometallics 2006, 25, 2230.
13. Kon, Y.; Ogasawara, J.; Sakamoto, K.; Kabuto, C.; Kira, M. J. Am. Chem. Soc. 2003, 125, 9310.
14. (a) Agh-Atabay, N. M.; Davidson, J. L.; Douglas, G.; Muir, K. W. J. Chem. Soc, Chem. Commun. 1989, 549. For a somewhat related iridacyclobutene resulting from a carbene insertion into a iridacyclopentadiene, see:
15. (b) O'Connor, J. M; Pu, L.; Woolard, S.; Chadha, R. K. J. Am. Chem. Soc. 1990, 112, 6731.
16. (a) Breslow, R.; Washburn, W.; Bergman, R. G. J. Am. Chem. Soc. 1969, 91, 196.
17. (b) Billups, W. E.; Saini, R. K.; Litosh, V. A.; Alemany, L. B.; Wilson, W. K.; Wiberg, K. B. J. Org. Chem. 2002, 67, 4436.
18. (c) Bajorek, T.; Werstink, N. H. Can. J. Chem. 2005, 83, 1352.
19. (a) Carmona, E.; Paneque, M.; Poveda, M. L. Dalton Trans. 2003, 4022.
20. (b) Carmona, E.; Paneque, M.; Santos, L. L.; Salazar, V. Coord. Chem. Rev. 2005, 294, 1729.
21. Brisdon, B. J.; Walton, R. A. Polyhedron 1995, 14, 1259.
22. Boutry, O.; Poveda, M. L.; Carmona, E. J. Organomet. Chem. 1997, 528, 143.
23. (a) Werner, H. J. Organomet. Chem. 1994, 475, 45.
24. (b) Werner, H.; Baum, M.; Schneider, D.; Windmueller, B. Organometallics 1994, 13, 1089.
25. (c) Werner, K; Lass, R. W.; Gevert, O.; Wolf, J. Organometallics 1997, 16, 4077.
26. (d) Jiménez, M. V.; Sola, E.; Lahoz, F. J.; Oro, L. A. Organometallics 2005, 24, 2722.
27. (e) Bustelo, E.; Carbó, J. J.; Lledés, A.; Mereiter, K.; Puerta, M. C.; Valerga, P. J. Am. Chem. Soc. 2003, 125, 3311.
28. (f) De Angelis, F.; Sgamellotti, A.; Re, N. Dalton Trans. 2004, 3225.
29. (a) Chin, C. S.; Lee, H. Chem.-Eur. J. 2004, 10, 4518.
30. (b) Clark, G. R.; Johns, P. M.; Roper, W. R.; Wright, L. J. Organometallics 2006, 25, 1771.
31. (c) O'Connor, J. M.; Hiibner, K.; Merwin, R.; Gantzel, P. K.; Fong, B. S.; Adams, M.; Rheingold, A. L. /Am. Chem. Soc. 1997, 119, 3631.
32. Broker programs: SMART, version 5.629; SAINT+, version 6.45; SADABS, version 2.10; SHELXTL, version 6.14; Bruker AXS Inc.: Madison, WI, 2003.
33. Sheldrick, G. M. SHELX97: Program System for Crystal Structure Determination; University of Gottingen: Göttingen, Germany, 1997.
34. Spek, A. L. PLATON: A Multipurpose Crystallography Tool; University of Utrecht: Utrecht, The Netherlands, 2006.