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Volumn 125, Issue 31, 2003, Pages 9310-9311

A stable silicon congener of highly strained bicyclo[3.2.0]hepta-1,3,6-triene

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; BICYCLO[3.2.0]HEPTA 1,3,6 TRIENE; SILICON; UNCLASSIFIED DRUG;

EID: 0043210664     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0359097     Document Type: Article
Times cited : (18)

References (19)
  • 10
    • 0041495087 scopus 로고    scopus 로고
    • note
    • 13C resonances is based on the GIAO/B3LYP/6-311+G** for a model compound. For the details of the calculations, see the Supporting Information.
  • 11
    • 0041495088 scopus 로고    scopus 로고
    • note
    • The thermal isomerization of 3 to 5 occurred at around 80 °C in solution. See the Supporting Information for the experimental details.
  • 12
    • 0002551588 scopus 로고    scopus 로고
    • For recent reviews of the reactivities of silenes with ketones, see: (a) Brook, A. G.; Brook, M. A. Adv. Organomet. Chem. 1996, 39, 71. (b) Müller, T.; Ziche, W.; Auner, N. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, 1998; Vol. 2, Chapter 16.
    • (1996) Adv. Organomet. Chem. , vol.39 , pp. 71
    • Brook, A.G.1    Brook, M.A.2
  • 13
    • 0002551588 scopus 로고    scopus 로고
    • Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, Chapter 16
    • For recent reviews of the reactivities of silenes with ketones, see: (a) Brook, A. G.; Brook, M. A. Adv. Organomet. Chem. 1996, 39, 71. (b) Müller, T.; Ziche, W.; Auner, N. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, 1998; Vol. 2, Chapter 16.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2
    • Müller, T.1    Ziche, W.2    Auner, N.3
  • 17
    • 0042496910 scopus 로고    scopus 로고
    • note
    • w = 0.082) for 5734 reflections with I > 5σ. GOF = 2.07.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.