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Volumn 26, Issue 14, 2007, Pages 3403-3415

Metallacycloheptatrienes of iridium(III): Synthesis and reactivity

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; OXIDATION; REACTION KINETICS;

EID: 34547311846     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om061036o     Document Type: Article
Times cited : (68)

References (60)
  • 7
    • 0010129413 scopus 로고
    • Abel, E. W, Stone, F. G. A, Wilkinson, G, Eds, Pergamon: Oxford, Chapter 7.3
    • (d) Grotjahn, D. B. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 12, Chapter 7.3.
    • (1995) Comprehensive Organometallic Chemistry II , vol.12
    • Grotjahn, D.B.1
  • 35
    • 34547297774 scopus 로고    scopus 로고
    • Carmona, E, Paneque, M, Santos, L. L, Salazar, V. Coord. Chem. Rev. 2005, 294, 1729. For some exceptions to this norm, see ref 8b and: Posadas. C. M. Ph.D. Thesis, University of Seville, 2006
    • (c) Carmona, E.; Paneque, M.; Santos, L. L.; Salazar, V. Coord. Chem. Rev. 2005, 294, 1729. For some exceptions to this norm, see ref 8b and: Posadas. C. M. Ph.D. Thesis, University of Seville, 2006.
  • 38
    • 34547307049 scopus 로고    scopus 로고
    • 3 is known and has been characterized, among other methods, by X-ray diffraction studies. See: (a) Hay-Motherwell, R. S.; Wilkinson, G.; Hussain-Bates, B.; Hursthouse, M. B. Polyhedron 1993, 12, 2009.
    • 3 is known and has been characterized, among other methods, by X-ray diffraction studies. See: (a) Hay-Motherwell, R. S.; Wilkinson, G.; Hussain-Bates, B.; Hursthouse, M. B. Polyhedron 1993, 12, 2009.
  • 40
    • 19944409309 scopus 로고    scopus 로고
    • 16 geometrical factors prevent the antibonding orbitals of the double bond Ir=O from being populated (although it is very reactive and easily transfers the oxo ligand to other reagents). Quite recently M=O derivatives for Pd and Pt have been described in which the double bond is protected by encapsulation. See: (a) Anderson, T. M.; Neiwert, W. A.; Kirk, M. L.; Piccoli, P. M. B.; Schulte, A. J.; Koetzle, T. F.; Musaev, D. G.; Morokuma, K.; Cao, R.; Hill, C. L. Science 2004, 306, 2074.
    • 16 geometrical factors prevent the antibonding orbitals of the double bond Ir=O from being populated (although it is very reactive and easily transfers the oxo ligand to other reagents). Quite recently M=O derivatives for Pd and Pt have been described in which the double bond is protected by encapsulation. See: (a) Anderson, T. M.; Neiwert, W. A.; Kirk, M. L.; Piccoli, P. M. B.; Schulte, A. J.; Koetzle, T. F.; Musaev, D. G.; Morokuma, K.; Cao, R.; Hill, C. L. Science 2004, 306, 2074.
  • 43
    • 34547328493 scopus 로고
    • Ley, S. V, Trost, B. M, Fleming, I, Eds, Pergamon: Oxford, Chapter 3.1
    • Somasekar, R. A. In Comprehensive Organic Chemistry; Ley, S. V., Trost, B. M., Fleming, I., Eds.: Pergamon: Oxford, 1991; Vol. 7, Chapter 3.1.
    • (1991) Comprehensive Organic Chemistry , vol.7
    • Somasekar, R.A.1
  • 59
    • 34547357884 scopus 로고    scopus 로고
    • Bruker programs: SMART, version 5.629; SAINT, version 6.45; SADABS, version 2.10; SHELXTL, version 6.14; Bruker AXS Inc, Madison, WI, 2003
    • Bruker programs: SMART, version 5.629; SAINT+, version 6.45; SADABS, version 2.10; SHELXTL, version 6.14; Bruker AXS Inc.: Madison, WI, 2003.
  • 60
    • 0004150157 scopus 로고    scopus 로고
    • Program System for Crystal Structure Determination; University of Göttingen, Göttingen, Germany
    • Sheldrick, G. M. SHELX97: Program System for Crystal Structure Determination; University of Göttingen, Göttingen, Germany, 1997.
    • (1997) SHELX97
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.