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We have not observed large differences in the outcomes of reactions conducted with the two salts. The synlanti ratio for products from cis-stilbene was 97/3 when 1P10Br was the initial salt in contact with the hexadecane layer as compared to 94/6 reported in Table 1 using 1P10Br3, However, use of 1P10Br3 is recommended in general because, in some cases, bromine that diffuses from below may react more slowly with the solid 1P10Br than it diffuses through the phosphonium layer and reacts with molecules in the upper hexadecane layer
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3 is recommended in general because, in some cases, bromine that diffuses from below may react more slowly with the solid 1P10Br than it diffuses through the phosphonium layer and reacts with molecules in the upper hexadecane layer.
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We have not compared as yet the regio- and stereoselectivities of brominations using 1P10Br3 and 1P10Br5. The configurations of our systems strongly suggest that 1P10Br3 is the dominant brominating agent in the work reported here
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3 is the dominant brominating agent in the work reported here.
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A slightly more sophisticated apparatus, which allows for the direct addition of bromine to the bottom layer and direct removal of the hexadecane layers, has been designed, and results from experiments in which it is used will be reported in the future
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A slightly more sophisticated apparatus, which allows for the direct addition of bromine to the bottom layer and direct removal of the hexadecane layers, has been designed, and results from experiments in which it is used will be reported in the future.
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