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A partial X-ray diffraction study on red crystals hand-picked from this crop has confirmed the presence of 2 in the mixture
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57
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85163237611
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It is noteworthy that such behaviour has already been observed by Tourné and Weakley in the 183W NMR spectrum of the [P 2W21O71(H2O)3] 6- anion, see ref.[59, However this degeneration was not observed for the free [P2W20O 70(H2O)2]10- or with its Bi 3+ and Sn4+ adducts, see ref.[63
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85163236530
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Actually, the solubility of the potassium salt of 1 remains insufficient to obtain the required concentrations for such time-consuming experiments and the signal-to-noise of the one-pulse 1D experiments does not allow the observation of all tungsten satellites. At that time all our attempts failed to prepare the pure lithium salt of 1, which is expected to be soluble enough for 2D-COSY experiments.
-
Actually, the solubility of the potassium salt of 1 remains insufficient to obtain the required concentrations for such time-consuming experiments and the signal-to-noise of the one-pulse 1D experiments does not allow the observation of all tungsten satellites. At that time all our attempts failed to prepare the pure lithium salt of 1, which is expected to be soluble enough for 2D-COSY experiments.
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This formula has been proposed on the hypothesis that 2 and 2′ are isomers. The W analysis has been performed by three different methods in order to confirm the systematical uncertainty of the results for heavy metals
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This formula has been proposed on the hypothesis that 2 and 2′ are isomers. The W analysis has been performed by three different methods in order to confirm the systematical uncertainty of the results for heavy metals.
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