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58149482272
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note
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1H NMR. Resonances for the exocyclic alkene proton, for all β-lactam cross products, were consistent with our NOE based E/Z assignments of α-alkylidene-β-lactones.
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22
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34247487884
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27
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58149494863
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note
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Interestingly, during the silica gel chromatographic purification of entry 4 (Table 2), there was significant isomerization of the exocyclic alkenes to the corresponding α,β-unsaturated esters (see Supplementary data).
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