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Volumn 140, Issue , 2008, Pages 147-189

Two-pathway excitation as a coherence spectroscopy

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EID: 58149266394     PISSN: 00652385     EISSN: None     Source Type: Book Series    
DOI: 10.1002/9780470371572.ch3     Document Type: Article
Times cited : (2)

References (86)
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    • We follow the convention adopted by the literature on coherent control via the one- versus three-photon excitation method, where the frequency of the three-photon field is denoted ω1 and that of the one-photon field is denoted ω3
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    • It is not essential that the electronic curves cross (at some level of approximation). In case they do not, however, they should become energetically degenerate in the atomic limit to be simultaneously observed. In the latter case kinetic (radial derivative) coupling is generally nonnegligible, because it is likely to become comparable to the energy separation before the potential curves become a constant function of the internuclear distance. See, for instance, S. J. Singer, K. F. Freed, and Y. B. Band, J. Chem. Phys. 79, 6060 (1983).
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    • We conform here to the convention of the condensed phase literature, where dephasing is used for lose of phase coherence (e.g., through collisions). It should be noted that this convention differs from that used in the wavepacket literature, where dephasing is used for a coherence-preserving process where anharmonicity of the underlying eigenvalue spectrum causes the wavepacket components to step out of phase but revivals occur provided that the motion is regular.
    • We conform here to the convention of the condensed phase literature, where "dephasing" is used for lose of phase coherence (e.g., through collisions). It should be noted that this convention differs from that used in the wavepacket literature, where "dephasing" is used for a coherence-preserving process where anharmonicity of the underlying eigenvalue spectrum causes the wavepacket components to step out of phase but revivals occur provided that the motion is regular.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.