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Volumn 111, Issue 20, 1999, Pages 9168-9182

Phase-sensitive observables as a route to understanding molecular continua

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EID: 0000906743     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.479831     Document Type: Article
Times cited : (25)

References (46)
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    • The classic example is the RKR method: J. R. Rydberg, Z. Phys. 73, 376 (1931); O. Klein, ibid. 76, 226 (1932); A. L. G. Rees, Proc. Phys. Soc. London 59, 998 (1946).
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    • note
    • ab in much of the previous literature and its origin is clear from Eq. (2). We avoid this term in the present paper so as not to risk confusion with the partial-wave phase shift of scattering theory.
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    • For theoretical studies of the autoionization spectroscopy of HI, see H. Lefebvre-Brion, A. Giusti-Suzor, and G. Raseev, J. Chem. Phys. 83, 1557 (1985). Experimental studies were reported by D. J. Hart and J. W. Hepburn, Chem. Phys. 129, 51 (1989). See also the work of A. Mank, M. Drescher, T. Huth-Fehre, N. Böwering, U. Heinzmann, and H. Lefebvre- Brion, J. Chem. Phys. 95, 1676 (1991).
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    • For theoretical studies of the autoionization spectroscopy of HI, see H. Lefebvre-Brion, A. Giusti-Suzor, and G. Raseev, J. Chem. Phys. 83, 1557 (1985). Experimental studies were reported by D. J. Hart and J. W. Hepburn, Chem. Phys. 129, 51 (1989). See also the work of A. Mank, M. Drescher, T. Huth-Fehre, N. Böwering, U. Heinzmann, and H. Lefebvre-Brion, J. Chem. Phys. 95, 1676 (1991).
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    • It is not essential that the electronic curves cross (at some level of approximation). In case they do not, however, they should become energetically degenerate in the atomic limit to be simultaneously observed. In the latter case kinetic (radial derivative) coupling is generally non-negligible since it is likely to become comparable to the energy separation before the potential curves become a constant function of the internuclear distance. See, for instance, S. J. Singer, K. F. Freed, and Y. B. Band, J. Chem. Phys. 79, 6060 (1983).
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