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The reaction of 3-methoxyphenyl propiolate under the conditions of Shi and He (ref. 8) affords a 1:3.5 ratio of 5-methoxy-2H-chromen-2-one and 7-methoxy-2H-chromen-2-one in 90% combined yield.
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The reaction of 3-methoxyphenyl propiolate under the conditions of Shi and He (ref. 8) affords a 1:3.5 ratio of 5-methoxy-2H-chromen-2-one and 7-methoxy-2H-chromen-2-one in 90% combined yield.
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X-ray crystallographic data for 6,6′-di-tert-butyl- 2H,2′H-3,3′-bichromen-2,2′-dione 3a: C26H26O4, Mr, 402.49, F(000, 3852; colorless needle; crystal size 0.05×0.07×0.44 mm; trigonal; space group R3̄c, a, 25.3197(3, b, 25.3197(3, c, 18.7196(6) Å; α=β= 90°, γ= 120°; V= 10393.1(4) Å3; Z, 18; ρcalcd, 1.157 Mgm-3. The crystal was measured on a Kappa APEX diffractometer at 173 K using graphite-monochromated MoKα radiation with λ, 0.71073 Å, Θmax, 27.471°. Minimal/maximal transmission 0.99/1.00, μ, 0.077 mm-1. The APEX suite has been used for data collection and integration.From a total of 42256 reflections, 2655 were independent merging r, 0.050, From these, 1815 were considered as obse
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[22] CCDC 690486 contains the supplementary crystallography data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif
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