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Volumn 14, Issue 35, 2008, Pages 10999-11009

Racemic β-sheets as templates for the generation of homochiral (isotactic) peptides from aqueous solutions of (RS)-valine or -leucine N-carboxy-anhydrides: relevance to biochirogenesis

Author keywords

Chirality; Oligopeptides; Self assembly; Sheet structures; Template synthesis

Indexed keywords

AMINATION; AMINES; AMINO ACIDS; CHEMICAL REACTIONS; CHIRALITY; DEUTERIUM; ENANTIOMERS; ESTERS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; MONOMERS; ORGANIC ACIDS; ORGANIC COMPOUNDS; POLYMERIZATION; POLYMERS; PROTEINS; SOLUTIONS; STEREOCHEMISTRY;

EID: 57149130562     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200801477     Document Type: Article
Times cited : (19)

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    • Similar kinetic effects can also account for the abundant formation of racemic crystals, particularly among the hydrophobic amino acids in nature, in comparison with conglomerates of enantiomorphous crystals
    • Similar kinetic effects can also account for the abundant formation of racemic crystals, particularly among the hydrophobic amino acids in nature, in comparison with conglomerates of enantiomorphous crystals.
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    • Such a model has not yet been proved experimentally in the polymerization of racemic amino acid activated derivatives
    • Such a model has not yet been proved experimentally in the polymerization of racemic amino acid activated derivatives.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.