메뉴 건너뛰기




Volumn 27, Issue 21, 2008, Pages 5494-5503

Synthesis, properties, and catalytic applications of caged, compact trialkylphosphine 4-phenyl-1-phospha-4-silabicyclo[2.2.2]octane

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC PHYSICS; ATOMS; CHELATION; COMPLEXATION; COORDINATION REACTIONS; ELECTRONIC PROPERTIES; HYDROSILYLATION; KETONES; LIGANDS; ORGANIC COMPOUNDS; PHOSPHORUS COMPOUNDS; PLATINUM; PLATINUM COMPOUNDS; POWDERS; RHODIUM; RHODIUM COMPOUNDS; SILICON; SULFUR COMPOUNDS; X RAY DIFFRACTION ANALYSIS;

EID: 56049107865     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om8005728     Document Type: Article
Times cited : (28)

References (39)
  • 7
    • 0000865745 scopus 로고    scopus 로고
    • For E = C, see: Jongsma, C.; De Kleijn, J. P.; Bickelhaupt, F. Tetrahedron 1974, 30, 3465-3469.
    • (a) For E = C, see: Jongsma, C.; De Kleijn, J. P.; Bickelhaupt, F. Tetrahedron 1974, 30, 3465-3469.
  • 11
    • 56049104806 scopus 로고    scopus 로고
    • For E = Si, see: Tsuji, H.; Inoue, T.; Kaneta, Y.; Sase, S.; Kawachi, A.; Tamao, K. Organometallics 2006, 25, 6142-6148. (f) For E = Ge, see: Rot, N.; De Wijs, W.-J. A.; De Kanter, F. J. J.; Dam, M. A.; Bickelhaupt, F.; Lutz, M.; Spek, A. L. Main Group Met. Chem. 1999, 22, 519-526.
    • (e) For E = Si, see: Tsuji, H.; Inoue, T.; Kaneta, Y.; Sase, S.; Kawachi, A.; Tamao, K. Organometallics 2006, 25, 6142-6148. (f) For E = Ge, see: Rot, N.; De Wijs, W.-J. A.; De Kanter, F. J. J.; Dam, M. A.; Bickelhaupt, F.; Lutz, M.; Spek, A. L. Main Group Met. Chem. 1999, 22, 519-526.
  • 14
    • 37049065077 scopus 로고    scopus 로고
    • For a diphosphine with a related structure, 1,4-diphosphabicyclo[2.2. 2]octane, see: Hinton, R. C.; Mann, F. G. J. Chem. Soc. 1959, 2835.
    • (a) For a diphosphine with a related structure, 1,4-diphosphabicyclo[2.2. 2]octane, see: Hinton, R. C.; Mann, F. G. J. Chem. Soc. 1959, 2835.
  • 21
    • 56049116366 scopus 로고    scopus 로고
    • For isolation of 14 and 15, see Supporting Information of ref la.
    • For isolation of 14 and 15, see Supporting Information of ref la.
  • 22
    • 56049111239 scopus 로고    scopus 로고
    • The corresponding 4JC-P has not been observed in 9-phospha-10-silatriptycenes [5 (R, Me, C12H 25) and other derivatives, See ref 5e
    • 25) and other derivatives]. See ref 5e.
  • 23
    • 0000083833 scopus 로고    scopus 로고
    • 3 (1.901 Å) determined by microwave spectroscopy. See: Bryan, P. S.; Kuczkowski, R. L. Inorg. Chem. 1972, 11, 553-559.
    • 3 (1.901 Å) determined by microwave spectroscopy. See: Bryan, P. S.; Kuczkowski, R. L. Inorg. Chem. 1972, 11, 553-559.
  • 24
    • 0032275043 scopus 로고    scopus 로고
    • The reason of the elongation is not clear at present. Correlation between steric/electronic properties of phosphines and P-B bond lengths are not clear in general. For a review, see: Brunel, J. M.; Faure, B.; Maffei, M. Coord. Chem. Rev. 1998, 178-180, 665-698.
    • (b) The reason of the elongation is not clear at present. Correlation between steric/electronic properties of phosphines and P-B bond lengths are not clear in general. For a review, see: Brunel, J. M.; Faure, B.; Maffei, M. Coord. Chem. Rev. 1998, 178-180, 665-698.
  • 26
    • 0001726382 scopus 로고    scopus 로고
    • The phosphine oxide form of 1-phosphabicyclo[2.2.2]octane was synthesized and its strain around the P atom was discussed. But it has not been converted to the free phosphine. See: Wetzel, R. B.; Kenyon, G. L J. Am. Chem. Soc. 1974, 96, 5189-5198.
    • The phosphine oxide form of 1-phosphabicyclo[2.2.2]octane was synthesized and its strain around the P atom was discussed. But it has not been converted to the free phosphine. See: Wetzel, R. B.; Kenyon, G. L J. Am. Chem. Soc. 1974, 96, 5189-5198.
  • 33
    • 56049087195 scopus 로고    scopus 로고
    • 3P as determined by GC analysis of 4-heptanol (isolation of the silyl ether product has not been attempted).
    • 3P as determined by GC analysis of 4-heptanol (isolation of the silyl ether product has not been attempted).
  • 34
    • 84879732150 scopus 로고    scopus 로고
    • de Vries, J. G, Elsevier, C. J, Eds, Wiley-VCH: Weinheim, Germany
    • Klomp, D.; Hanefeld, U.; Peters, J. A. In Handbook of Homogeneous Hydrogenation; de Vries, J. G., Elsevier, C. J., Eds.; Wiley-VCH: Weinheim, Germany, 2007; Vol. 2, pp 585-630.
    • (2007) Handbook of Homogeneous Hydrogenation , vol.2 , pp. 585-630
    • Klomp, D.1    Hanefeld, U.2    Peters, J.A.3
  • 36
    • 37049161285 scopus 로고    scopus 로고
    • Diisopropyl ketone (27) could not be reduced with Raney nickel or with nickel and some promoters, but was finally reduced with an equal weight of catalyst promoted with chloroplatinic acid and sodium hydroxide. See: Blance, R. B.; Gibson, D. T. J. Chem. Soc. 1954, 2487-2489.
    • (a) Diisopropyl ketone (27) could not be reduced with Raney nickel or with nickel and some promoters, but was finally reduced with an equal weight of catalyst promoted with chloroplatinic acid and sodium hydroxide. See: Blance, R. B.; Gibson, D. T. J. Chem. Soc. 1954, 2487-2489.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.