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Volumn 2, Issue 5, 2007, Pages 609-618

Phosphorus ligands with a large cavity: Synthesis of triethynylphosphines with bulky end caps and application to the rhodium-catalyzed hydrosilylation of ketones

Author keywords

Alkynylphosphines; Homogeneous catalysis; Ligand design; Rhodium; Silylacetylenes

Indexed keywords


EID: 34250852369     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.200700006     Document Type: Article
Times cited : (42)

References (40)
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    • The synthesis of 1a and 1b and their application to gold(I)-catalyzed alkyne cyclizations were reported preliminarily: A. Ochida, H. Ito, M. Sawamura, J. Am. Chem. Soc. 2006, 128, 16486-16487.
    • The synthesis of 1a and 1b and their application to gold(I)-catalyzed alkyne cyclizations were reported preliminarily: A. Ochida, H. Ito, M. Sawamura, J. Am. Chem. Soc. 2006, 128, 16486-16487.
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    • 0 complexes, see: M. A. Bennett, J. Castro, A. J. Edwards, M. R. Kopp, E. Wenger, A. C. Willis, Organometallics 2001, 20, 980-989.
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    • For the synthesis of 6, see reference [9b]; for the synthesis of 7, see: H. Hartmann, Justus Liebigs Ann. Chem. 1968, 714, 7.
    • For the synthesis of 6, see reference [9b]; for the synthesis of 7, see: H. Hartmann, Justus Liebigs Ann. Chem. 1968, 714, 7.
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    • We attempted X-ray diffraction analysis of the molecular structure of Ia. but the refinement is still insufficient (space group: R3, R= 15.9%) owing to serious disorder of the rBu groups; see the Supporting Information for a 3D model of la created on the basis of the insufficiently refined X-ray diffraction data.
    • We attempted X-ray diffraction analysis of the molecular structure of Ia. but the refinement is still insufficient (space group: R3, R= 15.9%) owing to serious disorder of the rBu groups; see the Supporting Information for a 3D model of la created on the basis of the insufficiently refined X-ray diffraction data.
  • 26
    • 22444436384 scopus 로고    scopus 로고
    • For the monocoordination of the bowl-shaped phosphine ligand (BSP) in [RhCl(cod)(BSP)], see: O. Niyomura, T. Iwasawa, N. Sawada, M. Tokunaga, Y. Obora, Y. Tsuji, Organometallics 2005, 24, 3468-3475.
    • For the monocoordination of the bowl-shaped phosphine ligand (BSP) in [RhCl(cod)(BSP)], see: O. Niyomura, T. Iwasawa, N. Sawada, M. Tokunaga, Y. Obora, Y. Tsuji, Organometallics 2005, 24, 3468-3475.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.