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Induction periods observed with a 1:2 ratio of Rh and 1c (< 15 min) and with a 1:3 ratio (30 min) can be attributed to suppression of active-species formation by an excess of the ligand at the early stage of the reaction. Although the reaction with 1:2 and 1:3 ratios was complete within 2 h, it afforded silylation product 14 in slightly diminished yields with the formation of small amounts of side products that could not be characterized.
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Induction periods observed with a 1:2 ratio of Rh and 1c (< 15 min) and with a 1:3 ratio (30 min) can be attributed to suppression of active-species formation by an excess of the ligand at the early stage of the reaction. Although the reaction with 1:2 and 1:3 ratios was complete within 2 h, it afforded silylation product 14 in slightly diminished yields with the formation of small amounts of side products that could not be characterized.
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4 remained unreacted and was insoluble in benzene. The supernatant solution was subjected to IR spectroscopy.
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4 remained unreacted and was insoluble in benzene. The supernatant solution was subjected to IR spectroscopy.
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This compound was prepared by a procedure similar to that for the synthesis of 3,5-bis(trimethylsilyl)bromobenzene, except for the use of tert-butyldimethylsilyl trifluoromethanesulfonate instead of trimethylsilyl chloride
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This compound was prepared by a procedure similar to that for the synthesis of 3,5-bis(trimethylsilyl)bromobenzene, except for the use of tert-butyldimethylsilyl trifluoromethanesulfonate instead of trimethylsilyl chloride.
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