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Volumn 47, Issue 43, 2008, Pages 8224-8227

A palladium-catalyzed dehydrogenative diamination of terminal olefins

Author keywords

Amination; Dehydrogenation; Palladium; Terminal olefins

Indexed keywords

ACETONE; AMINATION; AMINES; CHEMICAL REACTIONS; MATHEMATICAL TRANSFORMATIONS; PALLADIUM; PORT TERMINALS;

EID: 54249146835     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200803184     Document Type: Article
Times cited : (104)

References (49)
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    • For examples of metal-mediated diamination reactions, see: cobalt-mediated: a) P. N. Becker, M. A. White, R. G. Bergman, J. Am. Chem. Soc. 1980, 102, 5676;
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    • For recent copper(II)-mediated intramolecular diamination, see: a) T. P. Zabawa, D. Kasi, S. R. Chemler, J. Am. Chem. Soc. 2005, 127, 11250;
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    • For a recent example of palladium(II)-catalyzed intermolecular diamination of conjugated dienes, see: G. L. J. Bar, G. C. Lloyd-Jones, K. I. Booker-Milburn, J. Am. Chem. Soc. 2005, 127, 7308.
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    • For an example of copper(I)-catalyzed diamination using 4, see: B. Zhao, W. Yuan, H. Du, Y. Shi, Org. Lett. 2007, 9, 4943.
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    • Trace amounts of product resulting from diamination at the terminal carbon centers were formed for diene 6
    • Trace amounts of product resulting from diamination at the terminal carbon centers were formed for diene 6.
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    • For leading reviews on palladium(II)-catalyzed cyclization of N and O nucleophiles onto olefins, see: a) L. S. Hegedus, Tetrahedron 1984, 40, 2415;
    • For leading reviews on palladium(II)-catalyzed cyclization of N and O nucleophiles onto olefins, see: a) L. S. Hegedus, Tetrahedron 1984, 40, 2415;
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    • Internal diamination products from the resulting dienes were also observed
    • Internal diamination products from the resulting dienes were also observed.
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    • For leading references on the formation of dienes from [(π-allyl) Pd] complexes, see: a) Ref. [14a];
    • For leading references on the formation of dienes from [(π-allyl) Pd] complexes, see: a) Ref. [14a];


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