메뉴 건너뛰기




Volumn , Issue 2, 2003, Pages 211-214

A first asymmetric diamination of olefins

Author keywords

Asymmetric synthesis; Diamines; Diastereoselectivity; Imido complexes; Osmium

Indexed keywords

8 PHENYLMENTHOL; ALKENE; ESTER DERIVATIVE; IMIDAZOLINE DERIVATIVE; IMIDOOSMIUM; MENTHOL; OSMIUM; OSMIUM DERIVATIVE; UNCLASSIFIED DRUG;

EID: 0037281853     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-36799     Document Type: Article
Times cited : (64)

References (33)
  • 2
    • 0013356306 scopus 로고
    • PhD Thesis; Zaragoza: Spain
    • (b) Aznar, F. PhD Thesis; Zaragoza: Spain, 1975.
    • (1975)
    • Aznar, F.1
  • 20
    • 0013350760 scopus 로고    scopus 로고
    • note
    • Details on the full characterisation of new compounds, further substrates including studies on functional group tolerance, and X-ray structures of various racemic compounds will be given in a full account.
  • 21
    • 0013438689 scopus 로고    scopus 로고
    • note
    • 188Os: 724.3173, found: 724.3166.
  • 22
    • 0013356307 scopus 로고    scopus 로고
    • note
    • max = 50°), R1 = 0.0273 [I> 2sigma(I)], wR2 = 0.0613 (all data), 373 parameters and 44 restraints. Empirical absorption correction was applied. Crystallographic data (excluding structure factors) for the structure reported have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-192700. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax:+44 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
  • 26
    • 85087597277 scopus 로고    scopus 로고
    • note
    • 9 might be operating. Experimental and theoretical investigations addressing this question are underway.
  • 27
    • 0013438690 scopus 로고    scopus 로고
    • note
    • Apparently, this way of amide formation is not a general reaction. While it worked well for the present purpose, preliminary reactions indicated that it is not suitable for conventional N-alkylated α-amino esters. In these cases, the reaction proceeds very sluggishly and with complete racemization (K. Muñiz, unpublished results).
  • 29
    • 0013399283 scopus 로고    scopus 로고
    • note
    • 2O: C 73.33; H 10.86; N 10.06; found: C 73.62; H 11.01; N 9.89.
  • 30
    • 0013439318 scopus 로고    scopus 로고
    • note
    • 3O: C 67.32; H 12,36; N 14.72; found: C 66.95; H 12.22; N 15.01.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.