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Reproduction of selected NMR spectra can be found in the Supporting Information (for Supporting Information see also the footnote on the first page of this article).
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Details on the formation of the stereogenic metal centres are discussed in ref.[16] A relative [(2R,4R,5S)/(2S,4S,5R)]-configuration for the major diastereomers was assigned by X-ray analysis of the major diastereomer obtained from diamination of methyl cinnamate with compound 4. Details of this crystal structure analysis will be published elsewhere.
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