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For applications as a new class of highly productive, borate-free zwitterionic olefin polymerization catalysts, see: a M. Kranenbrug, G. H. J. Van Doremaele, B. Wang, M. A. Zuideveld, N. H. Friederichs, S. C. Lawrence, S. R. Dubberley, P. Mountford, 2005, WO 2005/123790;
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53949108221
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Although the term sandwich complex is conventionally used to describe bis(cyclopentadienyl) complexes it has been used in the literature to describe different ligand systems
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Although the term "sandwich" complex is conventionally used to describe bis(cyclopentadienyl) complexes it has been used in the literature to describe different ligand systems.
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138
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53949089741
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1HNMR resonances of the methyl substituents in the 3- and 5-positions of the pyrazolyl ring.
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1HNMR resonances of the methyl substituents in the 3- and 5-positions of the pyrazolyl ring.
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139
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B the Boltzman constant, T the absolute temperature, and η the viscosity of the solvent. It has been suggested that the factor r = 6 in the equation is not valid for small species whose van der Waals radii are <5 Å
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33644600662
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157
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84937798933
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2.234, To be consistent and facilitate comparisons we used the Stokes-Einslein equation as shown c, 6, although we recognise that perhaps a smaller value would be better
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