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Volumn 14, Issue 19, 2008, Pages 5918-5934

Syntheses, reactivity and DFT studies of group 2 and group 12 metal complexes of tris(pyrazolyl)methanides featuring "free" pyramidal carbanions

Author keywords

Density functional calculations; Magnesium; Tripodal ligands; Zinc; Zwitterions

Indexed keywords

METAL COMPLEXES;

EID: 53949091629     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200800181     Document Type: Article
Times cited : (59)

References (229)
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    • RTpmd: The superscript R denotes the substitutents in the 3- and the 5-posilions of the pyrazolyl ring.
    • RTpmd: The superscript R denotes the substitutents in the 3- and the 5-posilions of the pyrazolyl ring.
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    • Although the term sandwich complex is conventionally used to describe bis(cyclopentadienyl) complexes it has been used in the literature to describe different ligand systems
    • Although the term "sandwich" complex is conventionally used to describe bis(cyclopentadienyl) complexes it has been used in the literature to describe different ligand systems.
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    • We thank one reviewer of the manuscript for his suggestion.
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    • The metal frontier orbital involved in bonding to the methyl substituent is mainly of s and p type. For M = Zn partial contribution of d orbitais should not be totally excluded. See, for instance: T. A. Albright, J. K. Burdett, M. H. Whangbo, Orbital Interactions in Chemistry, Wiley-Interscience, New York, 1985.
    • The metal frontier orbital involved in bonding to the methyl substituent is mainly of s and p type. For M = Zn partial contribution of d orbitais should not be totally excluded. See, for instance: T. A. Albright, J. K. Burdett, M. H. Whangbo, Orbital Interactions in Chemistry, Wiley-Interscience, New York, 1985.
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