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Volumn 32, Issue 11, 1999, Pages 3820-3823

Half-metallocene-type ruthenium complexes as active catalysts for living radical polymerization of methyl methacrylate and styrene

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; DERIVATIVES; INITIATORS (CHEMICAL); METALLORGANIC POLYMERS; POLYMETHYL METHACRYLATES; POLYSTYRENES; RUTHENIUM COMPOUNDS;

EID: 0032652705     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma981798y     Document Type: Article
Times cited : (145)

References (45)
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    • For recent reviews on living/controlled radical polymerizations, see: (a) Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 365. (c) Mahnström, E. E.; Hawker, C. J. Macromol. Chem. Phys. 1998, 199, 823. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Controlled Radical Polymerization; Matyjaszewski, K. Ed.; ACS Symposium Series 685; American Chemical Society: Washington, DC, 1998. (g) Sawamoto, M.; Kamigaito, M. In Synthesis of Polymers; Schlüter, A.-D., Ed.; Materials Science and Technology Series; Wiley-VCH: Weinheim, Germany, 1999; Chapter 6.
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    • Schlüter, A.-D., Ed.; Materials Science and Technology Series; Wiley-VCH: Weinheim, Germany, Chapter 6
    • For recent reviews on living/controlled radical polymerizations, see: (a) Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Trends Polym. Sci. 1994, 2, 66. (b) Davis, T. P.; Kukulj, D.; Haddleton, D. M.; Maloney, D. R. Trends Polym. Sci. 1995, 3, 365. (c) Mahnström, E. E.; Hawker, C. J. Macromol. Chem. Phys. 1998, 199, 823. (d) Sawamoto, M.; Kamigaito, M. Trends Polym. Sci. 1996, 4, 371. (e) Colombani, D. Prog. Polym. Sci. 1997, 22, 1649. (f) Controlled Radical Polymerization; Matyjaszewski, K. Ed.; ACS Symposium Series 685; American Chemical Society: Washington, DC, 1998. (g) Sawamoto, M.; Kamigaito, M. In Synthesis of Polymers; Schlüter, A.-D., Ed.; Materials Science and Technology Series; Wiley-VCH: Weinheim, Germany, 1999; Chapter 6.
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    • Sawamoto, M.1    Kamigaito, M.2
  • 32
    • 13044281727 scopus 로고    scopus 로고
    • note
    • 1.15); Kyowa Chemical Industry Co., Ltd.] (ca. 5 g) to remove the metal-containing residues. After the absorbent was separated by filtration (Whatman 113V), the filtrate was washed with water and evaporated to dryness to give the products, which were subsequently vacuum-dried overnight.
  • 33
    • 13044250507 scopus 로고    scopus 로고
    • note
    • 1H NMR analysis were fractionated by preparative SEC (column: Shodex K-2002).
  • 41
    • 13044287394 scopus 로고    scopus 로고
    • note
    • 4
  • 43
    • 13044304590 scopus 로고    scopus 로고
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  • 44
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    • note
    • 5
  • 45
    • 13044309500 scopus 로고    scopus 로고
    • note
    • The poly(MMA)s obtained with 1 in toluene at 80°C were predominantly syndiotactic (rr:rm:mm = 57:38:4) and thus very similar in steric structure to poly(MMA) (e.g., rr:rm: mm = 58:38:4) radically prepared with AIBN in toluene at 80°C.


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