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note
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1.15); Kyowa Chemical Industry Co., Ltd.] (ca. 5 g) to remove the metal-containing residues. After the absorbent was separated by filtration (Whatman 113V), the filtrate was washed with water and evaporated to dryness to give the products, which were subsequently vacuum-dried overnight.
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1H NMR analysis were fractionated by preparative SEC (column: Shodex K-2002).
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The poly(MMA)s obtained with 1 in toluene at 80°C were predominantly syndiotactic (rr:rm:mm = 57:38:4) and thus very similar in steric structure to poly(MMA) (e.g., rr:rm: mm = 58:38:4) radically prepared with AIBN in toluene at 80°C.
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