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We determined the thermodynamic parameters from a van't Hoff plot, but this method does not give accurate parameters unless a broad temperature range can be accessed.
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We cannot eliminate the possibility that the different sizes of the peripheral alkoxy substituents have a role in the stacking. We have not observed significant substituent effects with other macrocycles, but they may be involved here. Efforts are underway to prepare new analogues that will allow better control of the substituents
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We cannot eliminate the possibility that the different sizes of the peripheral alkoxy substituents have a role in the stacking. We have not observed significant substituent effects with other macrocycles, but they may be involved here. Efforts are underway to prepare new analogues that will allow better control of the substituents.
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