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For the preferential transformation of an aromatic over an aliphatic C-H bond, see, for example
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The acetate anion was reported to favor norbornene insertion. See, for example
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The acetate anion was reported to favor norbornene insertion. See, for example: M. C. Gallazzi, L. Porri, G. Vitulli, J. Organomet. Chem. 1975, 97, 131.
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and references cited therein. For a rational interpretation of the use of bases see
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For a rational interpretation of the use of bases see: M. Lafrance, A. K. Fagnou, J. Am. Chem. Soc. 2006, 128, 16496, and references cited therein.
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53849130481
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To our knowledge compounds of type 10 and 11 have not been prepared so far under the conditions of a conventional Heck reaction from aryl vinyl ethers, probably owing to the instability of the latter.
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To our knowledge compounds of type 10 and 11 have not been prepared so far under the conditions of a conventional Heck reaction from aryl vinyl ethers, probably owing to the instability of the latter.
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20
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53849122150
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Analogously, no double bond formation was obtained under our conditions with substituents offering steric hindrance or unsuitable conformation such as for example o,o-diethyl and o,o-diisopropyl.
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Analogously, no double bond formation was obtained under our conditions with substituents offering steric hindrance or unsuitable conformation such as for example o,o-diethyl and o,o-diisopropyl.
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