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note
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Attempts to cyclize o-iodoaryl allylic ethers to products having two fused five-membered rings have proven unsuccessful, presumably due to the greater distance the Pd must migrate in these systems as opposed to the six-membered ring intermediates and the strain present in the resulting products.
-
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29
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0035354658
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and references therein
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For mechanistic studies suggesting electrophilic species in intramolecular C-H activation by palladium, see: (a) Martin-Matute, B.; Mateo, C.; Cardenas, D. J.; Echavarren, A. M. Chem.-Eur. J. 2001, 7, 2341-2348 and references therein.
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