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Data collections for the crystal-structure analysis were performed on a Nonius KCCD diffractometer equipped with a Cryostream cooler with graphite-monochromated MoKα radiation (λ, 0.7107 Å, The samples were measured at 120 K. The structures were solved by direct methods (Shelxs) and refined on F with anisotropic temperature factors for the non-hydrogen atoms. The H atoms were refined with fixed isotropic temperature factors in the riding mode. 5a: C26H16O 2, Mr 360.41 gmol-1. monoclinic. space group P21/a, a, 16.0660(6, b, 4.5830(4, c, 23.2180(7) Å β, 99.842(1)°, V, 1684.39(17) Å, Z, 4. ρeated, 1.421 gem3, μ, 0.089. 2θmax, 27.496°, 22586 reflections measured, 3817 unique. 1854 observed, Riot, 0.087, R, 0.0519, Rμ, 0.0432; 5b: C28H20O 4, Mr
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μ = 0.0536; CCDC-678259, CCDC-678260, and CCDC-678261 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
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