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Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publications nos. CCDC-680900 (compound 7) and CCDC-680901 (compound 11, Copies of data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. For compound 7, the torsion angles N1C1C2N2 and C3C1C2C4 are-61,74(5)° and 62.3(4)°, respectively, with the N amine atoms and the methyl groups in a gauche conformation. The phenyl moieties are almost perpendicular to each other with an angle of 82.9(1)° between the corresponding aromatic planes. For compound 11 a crystallographic 2-fold axis passes through the Cl atom; thus the molecular 2-fold symmetry is retained also in the crystals. The five-atom ring and the phenyl moieties are planar within a rmsd of respectively 0.013 and 0.006 Å; they are almo
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Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publications nos. CCDC-680900 (compound 7) and CCDC-680901 (compound 11). Copies of data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. For compound 7, the torsion angles N1C1C2N2 and C3C1C2C4 are-61,74(5)° and 62.3(4)°, respectively, with the N amine atoms and the methyl groups in a gauche conformation. The phenyl moieties are almost perpendicular to each other with an angle of 82.9(1)° between the corresponding aromatic planes. For compound 11 a crystallographic 2-fold axis passes through the Cl atom; thus the molecular 2-fold symmetry is retained also in the crystals. The five-atom ring and the phenyl moieties are planar within a rmsd of respectively 0.013 and 0.006 Å; they are almost perpendicular to each other, the angle between the two planes being 84.5(1)°. The torsion angle C5-C4-C6-C11 is-92.0(4)°.
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