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Volumn , Issue 25, 2008, Pages 3977-3986

Syntheses, characterization, and reactivities of (μ-η2: η2-disulfido)dicopper(II) complexes with N-alkylated cis,cis-1,3,5-triaminocyclohexane derivatives

Author keywords

Dicopper complexes; Dihedral angles; Disulfide; Triaminocyclohexane

Indexed keywords

ABSORPTION SPECTROSCOPY; COPPER COMPOUNDS; CRYSTAL ATOMIC STRUCTURE; RAMAN SCATTERING; RUTHENIUM COMPOUNDS; SPECTROSCOPIC ANALYSIS; SULFUR COMPOUNDS; SYNTHESIS (CHEMICAL);

EID: 53549087803     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200701358     Document Type: Article
Times cited : (5)

References (57)
  • 51
    • 85163248146 scopus 로고    scopus 로고
    • The reduction peaks of [Cu2(OH)2(R 3TACH)2]2, R, Et, iBu, and Bn) were observed at -455, 448, and -465 mV vs, Fe(C5H5) 2, Fe(C5H5)2, and the oxidation peaks were observed at -343, 89, and 189 mV for [Cu 2(OH)2(Et3TACH)]2, 281, 41, and 129 mV for [Cu2(OH)2(iBu3TACH) 2]2, 363, 73, and 153 mV for [Cu2(OH) 2(Bn3TACH)2]2, respectively. Among these oxidation peaks, two additional positive peaks were observed that may represent oxidation waves of other complexes formed from the reaction of bis(μ-OH)dicopper complexes with the DMF electrolyte
    • 2+, respectively. Among these oxidation peaks, two additional positive peaks were observed that may represent oxidation waves of other complexes formed from the reaction of bis(μ-OH)dicopper complexes with the DMF electrolyte.


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