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Volumn 44, Issue 47, 2005, Pages 7745-7748

Characterization of a complex comprising a {Cu2(S 2)2}2+ core: Bis(μ-S2 2-)dicopper(III) or bis(μ-S2.-)dicopper(II)?

Author keywords

Bioinorganic chemistry; Bridging ligands; Copper; N ligands; Sulfur

Indexed keywords

COPPER COMPOUNDS; SPECTROSCOPIC ANALYSIS; STRUCTURE (COMPOSITION); SULFUR;

EID: 28744449774     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200503134     Document Type: Article
Times cited : (54)

References (57)
  • 13
    • 28744447737 scopus 로고    scopus 로고
    • note
    • Abbreviations used: tmeda = N,N,N′,N′- tetramethylethylenediamine; tmchd = N,N,N′,N′- tetramethylcyclohexane-1,2-diamine; OTf = trifluoromethanesulfonate.
  • 19
    • 84977289324 scopus 로고
    • X-ray structural analysis of 3: An X-ray quality crystal was mounted on a Siemens SMART Platform CCD diffractometer for data collection. A randomly oriented region of reciprocal space was surveyed to the extent of one sphere and to a resolution of 0.84 Å. The intensity data were corrected for absorption and decay by using SADABS (R. Blessing, Acta Crystallogr. Sect. A 1995, 51, 33).
    • (1995) Acta Crystallogr. Sect. A , vol.51 , pp. 33
    • Blessing, R.1
  • 20
    • 0004022783 scopus 로고    scopus 로고
    • Bruker Analytical X-ray Systems, Madison, WI
    • Final cell constants were calculated from the xyz centroids of strong reflections from the actual data collection after integration with SAINT (SAINT version 6.2, Bruker Analytical X-ray Systems, Madison, WI, 2001).
    • (2001) SAINT Version 6.2
  • 21
    • 0004150157 scopus 로고    scopus 로고
    • Bruker Analytical X-Ray Systems, Madison, WI
    • -3. The crystallographic data for the two forms of 2 are given in the Supporting Information. CCDC-282801-282803 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
    • (2000) SHELXTL Version 6.10
  • 22
    • 0034583335 scopus 로고    scopus 로고
    • .- ion is often referred to as "supersulfide" in the literature, but, according to the IUPAC recommendations, it should be denoted as "disulfide(.1-)"; see: W. H. Koppenol, Pure Appl. Chem. 2000, 72, 437.
    • (2000) Pure Appl. Chem. , vol.72 , pp. 437
    • Koppenol, W.H.1
  • 54
    • 0041523717 scopus 로고
    • Measured in crystalline KI: J. Rolfe, J. Chem. Phys. 1968, 49, 4193.
    • (1968) J. Chem. Phys. , vol.49 , pp. 4193
    • Rolfe, J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.