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40949112060
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Abbreviations: Me4pda, N,N,N′,N′- tetramethylpropanediamine, Me3tacn, 1,4,7-trimethyl-1,4,7- triazacyclononane, Me4chd, N,N,N′,N′- tetramethyl-trans-1(R),2(R)-diammocyclohexane
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4chd = N,N,N′,N′- tetramethyl-trans-1(R),2(R)-diammocyclohexane.
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26
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40949161579
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The relationship between the S-S separation and ν(S-S) may be quantified by Badger's rule, as described in reference [11d, From the observed S-S distances, the predicted ν(S-S) values are 481 cm-1 (1) and 444 cm-1 (2, The value for 1 is in excellent agreement with that observed by Raman spectroscopy. We attribute the poorer agreement for 2 to the more complicated set of features in the 400-500 cm-1 region of the spectrum for this compound arising from coupling of vibrational modes i.e. the strong peak at 477 cm-1 is likely not a pure S-S stretch
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-1 is likely not a pure S-S stretch).
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27
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0037024169
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a) M. Taki, S. Teramae, S. Nagatomo, Y. Tachiu, T. Kitagawa, S. Itoh, S. Fukuzume, J. Am. Chem. Soc. 2002, 124, 6367-6377;
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Fukuzume, S.7
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29
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40949130156
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2 with 9,10-dihydroanthracene, THF, or aniline (RT, 2-4 h).
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2 with 9,10-dihydroanthracene, THF, or aniline (RT, 2-4 h).
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31
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0033575068
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34
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40949132238
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2.
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2.
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35
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27544455441
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The O3SCF3- salt of this complex has been reported
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- salt of this complex has been reported: A. P. Cole, V. Mahadevan, L. M. Mirica, X. Ottenwaelder, T. D. P. Stack, Inorg. Chem. 2005, 44, 7345-7364.
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Cole, A.P.1
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Stack, T.D.P.5
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