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Volumn 47, Issue 3, 2008, Pages 533-536

Novel reactivity of side-on (disulfido)dicopper complexes supported by bi- and tridentate nitrogen donors: Impact of axial coordination

Author keywords

Copper; Disulfide; Oxidation; Sulfur

Indexed keywords

COMPLEXATION; LIGANDS; OXIDATION; REDOX REACTIONS;

EID: 38949171435     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200704690     Document Type: Article
Times cited : (25)

References (35)
  • 6
    • 4544231537 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2004, 43, 4132-4140;
    • (2004) Angew. Chem. Int. Ed , vol.43 , pp. 4132-4140
  • 14
    • 28744449774 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 7745-7748.
    • (2005) Angew. Chem. Int. Ed , vol.44 , pp. 7745-7748
  • 23
    • 33746313193 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 1138-1141;
    • (2006) Angew. Chem. Int. Ed , vol.45 , pp. 1138-1141
  • 25
    • 40949112060 scopus 로고    scopus 로고
    • Abbreviations: Me4pda, N,N,N′,N′- tetramethylpropanediamine, Me3tacn, 1,4,7-trimethyl-1,4,7- triazacyclononane, Me4chd, N,N,N′,N′- tetramethyl-trans-1(R),2(R)-diammocyclohexane
    • 4chd = N,N,N′,N′- tetramethyl-trans-1(R),2(R)-diammocyclohexane.
  • 26
    • 40949161579 scopus 로고    scopus 로고
    • The relationship between the S-S separation and ν(S-S) may be quantified by Badger's rule, as described in reference [11d, From the observed S-S distances, the predicted ν(S-S) values are 481 cm-1 (1) and 444 cm-1 (2, The value for 1 is in excellent agreement with that observed by Raman spectroscopy. We attribute the poorer agreement for 2 to the more complicated set of features in the 400-500 cm-1 region of the spectrum for this compound arising from coupling of vibrational modes i.e. the strong peak at 477 cm-1 is likely not a pure S-S stretch
    • -1 is likely not a pure S-S stretch).
  • 29
    • 40949130156 scopus 로고    scopus 로고
    • 2 with 9,10-dihydroanthracene, THF, or aniline (RT, 2-4 h).
    • 2 with 9,10-dihydroanthracene, THF, or aniline (RT, 2-4 h).
  • 34
    • 40949132238 scopus 로고    scopus 로고
    • 2.
    • 2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.