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Volumn 130, Issue 40, 2008, Pages 13465-13470

Atomic contacts via electrochemistry in water/cyclodextrin media: A step toward protected atomic contacts

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; NANOELECTRONICS; SENSORS;

EID: 53549087562     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja804680w     Document Type: Article
Times cited : (28)

References (35)
  • 23
    • 53549095137 scopus 로고    scopus 로고
    • It is quite surprising that atomic contacts can be obtained without any supporting electrolyte. The intrinsic solution conductivity and potential distribution in the microgap is therefore at the mercy of dissolved gases and contamination (thanks to one of the referees for this comment, Nevertheless, it is with this unconventional electrolyte that we obtain the best reproducibility using the self-terminated method. We believe that the slow and smooth interpenetration of the large diffuse layers of the two electrodes getting closer is a key to understanding this effect. We are currently working on this particular observation we believe also that contamination is at the origin of the few below 1 G0 atomic contacts generated in water that are sometimes observed
    • 0 atomic contacts generated in water that are sometimes observed).
  • 24
    • 0007233796 scopus 로고    scopus 로고
    • Harata, K. Chem. Rev. 1998, 98, 1803-1827.
    • (1998) Chem. Rev , vol.98 , pp. 1803-1827
    • Harata, K.1
  • 35
    • 53549101849 scopus 로고    scopus 로고
    • 0 atomic contacts generated in water and then exposed to cyclodextrins and finally to salicylate always break a few seconds after salicylate injection. This shows that β-CD has to be present during generation of the contact to obtain protection against salicylate; added subsequently it does not protect the contact.
    • 0 atomic contacts generated in water and then exposed to cyclodextrins and finally to salicylate always break a few seconds after salicylate injection. This shows that β-CD has to be present during generation of the contact to obtain protection against salicylate; added subsequently it does not protect the contact.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.