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Hampel, F.2
Gladysz, J.A.3
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70
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84981775322
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b) I. Ugi, U. Fetzer, U. Eholzer, H. Knupfer, K. Offermann, Angew. Chem. Int. Ed. Engl. 1965, 4, 472-484.
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(1965)
Angew. Chem. Int. Ed. Engl
, vol.4
, pp. 472-484
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-
Ugi, I.1
Fetzer, U.2
Eholzer, U.3
Knupfer, H.4
Offermann, K.5
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71
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85163226360
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D = C(fluorous phase)/C(organic phase) to be 93.9:6.1 at 25°C. A known amount of the fluorous compound (40-70 mg) was dissolved in the biphasic system [perfluorocyclohexane/toluene (1:1, v/v); 4 mL]. The resulting mixture was vigorously stirred in a 10 mL vial immersed in a 25°C oil bath for 24 h. After two clear layers were obtained, an aliquot was removed from each layer with a syringe and added to the hexane standard. The partition coefficients were calculated based upon the ratio of the integration of the GC from both phases (average of four runs). The partition coefficient for 6 was 94.5:5.5.
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D = C(fluorous phase)/C(organic phase) to be 93.9:6.1 at 25°C. A known amount of the fluorous compound (40-70 mg) was dissolved in the biphasic system [perfluorocyclohexane/toluene (1:1, v/v); 4 mL]. The resulting mixture was vigorously stirred in a 10 mL vial immersed in a 25°C oil bath for 24 h. After two clear layers were obtained, an aliquot was removed from each layer with a syringe and added to the hexane standard. The partition coefficients were calculated based upon the ratio of the integration of the GC from both phases (average of four runs). The partition coefficient for 6 was 94.5:5.5.
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72
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85163231233
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Efforts to obtain a solution suitable for the acquisition of an NMR spectrum were unsuccessful in the case of Ag complexes
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Efforts to obtain a solution suitable for the acquisition of an NMR spectrum were unsuccessful in the case of Ag complexes.
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73
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37049082342
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A. Toth, C. Floriani, A. Chiesi-Villa, C. Guastini, J. Chem. Soc., Dalton Trans. 1988, 1599-1605.
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(1988)
J. Chem. Soc., Dalton Trans
, pp. 1599-1605
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Toth, A.1
Floriani, C.2
Chiesi-Villa, A.3
Guastini, C.4
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74
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85163231361
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The 2°C mesophase range for 8 was observed under a polarized microscope, the DSC scan displayed only one peak.
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The 2°C mesophase range for 8 was observed under a polarized microscope, the DSC scan displayed only one peak.
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-
-
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75
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0037619084
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T. Hegmann, J. Kain, S. Diele, B. Schubert, H. Bögel, C. Tschierske, J. Mater. Chem. 2003, 13, 991-1003.
-
(2003)
J. Mater. Chem
, vol.13
, pp. 991-1003
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Hegmann, T.1
Kain, J.2
Diele, S.3
Schubert, B.4
Bögel, H.5
Tschierske, C.6
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77
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37049109848
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R. Usón, J. Forniés, F. Martínez, M. Tomás, J. Chem. Soc., Dalton Trans. 1980, 888-894.
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(1980)
J. Chem. Soc., Dalton Trans
, pp. 888-894
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Usón, R.1
Forniés, J.2
Martínez, F.3
Tomás, M.4
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78
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85163226310
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1H NMR spectrum.
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1H NMR spectrum.
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-
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79
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85163227893
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The assignment of the aromatic signals was based on the spectroscopic data of formamides in ref.[17g
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[17g]
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-
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80
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85163225261
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The formation of bis(isocyanide) complex Fe(CO)3(CNAr) 2 [Ar, 4-F(CF2)8(CH2) 4OC6H4] as a side product was observed; it was isolated and characterized. C41H24F34FeN 2O5 (1326.43, calcd. C 37.13, H 1.82, N 2.11; found C 36.65, H 1.94, N 1.83. IR: ν, 2114 [ν(N≡C, 1999, 1932 [ν(C=O, cm-1. 1H NMR (CDCl3, δ, 7.27 (d, J, 8.8 Hz, 2 H, ortho to NC, 6.87 (d, J, 8.8 Hz, 2 H, meta to NC, 4.02 (t, J, 5.4 Hz, 2 H, OCH2, 2.40-2.05 (m, 2 H, CH2CF2, 2.05-1.85 [m, 4 H, CH2)2CH2CF2] ppm
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2] ppm.
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