Chemical dynamics of vibrationally excited molecules: Controlling reactions in gases and on surfaces

Proceedings of the National Academy of Sciences of the United States of America

Volumn 105, Issue 35, 2008, Pages 12654-12661

  Crim, F Fleming ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COLLISIONALLY ACTIVATED DISSOCIATION; DISSOCIATION; ENERGY TRANSFER; ISOMERIZATION; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; PRIORITY JOURNAL; REACTION ANALYSIS; REVIEW; VIBRATION;

EID: 51349168270     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.0803010105     Document Type: Review

References (69)

1. Levine RD Bernstein RB (1987) Molecular Reaction Dynamics and Chemical Reactivity (Oxford Univ Press, New York).
2. Brouard M (1998) Reaction Dynamics (Oxford Univ Press, New York).
3. Clary DC (2008) Theoretical studies on bimolecular reaction dynamics. Proc Natl Acad Sci USA 105:12649-12653.
4. Crim FF (1999) Vibrational state control of bimolecular reactions: Discovering and directing the chemistry. Acc Chem Res 32:877-884.
5. Elles CG, Crim FF (2006) Connecting chemical dynamics in gases and liquids. Annu Rev Phys Chem 57:273-302.
6. 2 from Ag(111). 1. Rotational populations and alignment. J Chem Phys 89:2558-2571.
7. Tang SL, Lee MB, Beckerle JD, Hines MA, Ceyer ST (1985) Effect of translational energy on chemisorption: Evidence for a precursor to molecular chemisorption. J Chem Phys 82:2826-2827.
8. Hou H, et al. (1999) Enhanced reactivity of highly vibrationally excited molecules on metal surfaces. Science 284:1647-1650.
9. 3) dissociation on Ni(100). Phys Rev Lett 83:868-871.
10. Juurlink LBF, Smith RR, Utz AL (2000) The role of rotational excitation in the activated dissociative chemisorption of vibrationally excited methane on Ni(100). Faraday Discuss 117:147-160.
11. Juurlink LBF, Smith RR, Utz AL (2000) Controlling surface chemistry with light: Spatially resolved deposition of rovibrational-state-selected molecules. J Phys Chem B 104:3327-3336.
12. 3) on Ni(100). J Chem Phys 117:8603-8606.
13. Beck RD, et al. (2003) Vibrational mode-specific reaction of methane on a nickel surface. Science 302:98-100.
14. Smith RR, Killelea DR, DelSesto DF, Utz AL (2004) Preference for vibrational over translational energy in a gas-surface reaction. Science 304:992-995.
15. Juurlink LBF, Smith RR, Killelea DR, Utz AL (2005) Comparative study of C-H stretch and bend vibrations in methane activation on Ni(100) and Ni(111). Phys Rev Lett 94:208303.
16. Maroni P, et al. (2005) State-resolved gas-surface reactivity of methane in the symmetric C-H stretch vibration on Ni(100). Phys Rev Lett 94:246104.
17. 3) on Pt(111) and Ni(111): Effects of barrier height and transition state location. J Phys Chem A 111:12679-12683.
18. Killelea DR, Campbell VL, Shuman NS, Utz AL (2008) Bond-selective control of a heterogeneously catalyzed reaction. Science 319:790-793.
19. 3) activation of the chemisorption of methane on Pt (111). J Chem Phys 114:5277-5283.
20. Nathanson GM (2004) Molecular beam studies of gas-liquid interfaces. Annu Rev Phys Chem 55:231-255.
21. Saecker ME, Govoni ST, Kowalski DV, King ME, Nathanson GM (1991) Molecular-beam scattering from liquid surfaces. Science 252:1421-1424.
22. Vazquez SA, et al. (2007) Inelastic scattering dynamics of Ar from a perfluorinated self-assembled monolayer surface. J Phys Chem A 111:12785-12794.
23. 2 scattering dynamics at the gas-liquid interface: Dependence on incident angle. J Phys Chem A 111:7420-7430.
24. Perkins BG, Nesbitt DJ (2008) Stereodynamics in state-resolved scattering at the gas-liquid interface Proc Natl Acad Sci USA 105:12684-12689.
25. Owrutsky JC, Raftery D, Hochstrasser RM (1994) Vibrational relaxation dynamics in solutions. Annu Rev Phys Chem 45:519-555.
26. Sension RJ, Repinec ST, Szarka AZ, Hochstrasser RM (1993) Femtosecond laser studies of the cis-stilbene photoisomerization reactions. J Chem Phys 98:6291-6315.
27. Raftery D, Iannone M, Phillips CM, Hochstrasser RM (1993) Hydrogen abstraction dynamics in solution studied by picosecond infrared spectroscopy. Chem Phys Lett 201:513-520.
28. Raftery D, Gooding E, Romanovsky A, Hochstrasser RM (1994) Vibrational product state dynamics in solution phase bimolecular reactions: Transient infrared study of CN radical reactions. J Chem Phys 101:8572-8579.
29. Sheps L, Crowther AC, Elles CG, Crim FF (2005) Recombination dynamics and hydrogen abstraction reactions of chlorine radicals in solution. J Phys Chem A 109:4296-4302.
30. 11 in solution. J Phys Chem A 110:3087-3092.
31. 3. J Chem Phys 112:9375-9389.
32. 3 on an ab initio potential. Phys Chem Chem Phys 9:933-943.
33. 4 reaction dynamics on a quadratic configuration interaction with single and double excitation interpolated potential energy surface. J Chem Phys 125:124316.
34. 3 preferentially promote reactivity toward the chlorine atom? Science 316:1723-1726.
35. 3. Chem Phys Lett 212:163-171.
36. 4 reaction. J Chem Phys 122:101102.
37. 3/2). J Chem Phys 119:4755-4761.
38. 3D molecules with excited symmetric and antisymmetric stretching vibrations. J Chem Phys 119:9568-9575.
39. 3D with Cl. J Phys Chem B 109:8388-8392.
40. -1. J Chem Phys 125:133101.
41. Kim ZH, Bechtel HA, Zare RN (2001) Vibrational control in the reaction of methane with atomic chlorine. J Am Chem Soc 123:12714-12715.
42. 2. J Chem Phys 120:791-799.
43. Camden JP, Bechtel HA, Brown DJA, Zare RN (2006) Comparing reactions of H and Cl with C-H stretch-excited CHD3. J Chem Phys 124:034311.
44. 2O. J Chem Phys 116:1406-1416.
45. Halonen L, Bernasek SL, Nesbitt DJ (2001) Reactivity of vibrationally excited methane on nickel surfaces. J Chem Phys 115:5611-5619.
46. Bechtel HA, et al. (2005) Effects of bending excitation on the reaction of chlorine atoms with methane. Angew Chem Int Ed 44:2382-2385.
47. 3D molecules containing both C-H and C-D stretching excitation. J Phys Chem A, in press.
48. Polanyi JC (1972) Some concepts in reaction dynamics. Acc Chem Res 5:161-168.
49. Yan S, Wu Y-T, Liu K (2008) Tracking the energy flow along the reaction path. Proc Natl Acad Sci USA 105:12667-12672.
50. 3: State-to-state differential cross-sections and steric effects for the HCl product. J Chem Phys 103:7313-7335.
51. Schmid MP, Maroni P, Beck RD, Rizzo TR (2003) Molecular-beam/surface- science apparatus for state-resolved chemisorption studies using pulsed-laser preparation. Rev Sci Instrum 74:4110-4120.
52. McCabe PR, Juurlink LBF, Utz AL (2000) A molecular beam apparatus for eigenstate-resolved studies of gassurface reactivity. Rev Sci Instrum 71:42-53.
53. Maroni P, Papageorgopoulos D, Ruf A, Beck RD, Rizzo TR (2006) Efficient stimulated Raman pumping for quantum state resolved surface reactivity measurements. Rev Sci Instrum 77:054103.
54. 2:Watching energy flow in solution. J Chem Phys 113:5018-5025.
55. 2 molecules in solution. J Phys Chem A 105:5071-5080.
56. 5I molecules in solution. Phys Chem Chem Phys 3:2230-2240.
57. 2 fundamental vibrational relaxation in solution studied by transient electronic absorption spectroscopy. J Chem Phys 115:7086-7093.
58. Assmann J, et al. (2002) Real-time observation of intra- and intermolecular vibrational energy flow of selectively excited alkyl iodides in solution: The effect of chemical substitution. J Phys Chem A 106:5197-5201.
59. 3I in solution. J Chem Phys 117:8917-8925.
60. 2 in solution: Excitation level dependence. J Chem Phys 118:5587-5595.
61. 3I in the gas phase and in solution. J Chem Phys 120:6973-6979.
62. 2: Measurements from the gas phase up to liquid densities. Chem Phys Lett 386:325-329.
63. Yoo HS, DeWitt MJ, Pate BH (2004) Vibrational dynamics of terminal acetylenes. I. Comparison of the intramolecular vibrational energy redistribution rate of rases and the total relaxation rate of dilute solutions at room temperature. J Phys Chem A 108:1348-1364.
64. Yoo HS, DeWitt MJ, Pate BH (2004) Vibrational dynamics of terminal acetylenes. II. Pathway for vibrational relaxation in gas and solution. J Phys Chem A 108:1365-1379.
65. Bonn M, Brugmans MJP, Bakker HJ (1996) Solvent-dependent vibrational relaxation pathways after successive resonant IR excitation to v=2. Chem Phys Lett 249:81-86.
66. van den Broek M, Bakker HJ (2000) Observation of a bottleneck in the vibrational relaxation of liquid bromoform. Chem Phys 253:157-164.
67. Graener H, Zurl R, Hofmann M (1997) Vibrational relaxation of liquid chloroform. J Phys Chem B 101:1745-1749.
68. Seifert G, Zurl R, Patzlaff T, Graener H (2000) Time-resolved observation of intermolecular vibrational energy transfer in liquid bromoform. J Chem Phys 112:6349-6354.
69. Graener H, Patzlaff T, Kadarisman N, Seifert G (2001) Observation of intensity-dependent, nonexponential vibrational relaxation in liquid bromoform. Chem Phys Lett 348:403-410.