Vibrational state control of bimolecular reactions: Discovering and directing the chemistry

Accounts of Chemical Research

Volumn 32, Issue 10, 1999, Pages 877-884

  Crim, F Fleming ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANALYTIC METHOD; ARTICLE; CHEMICAL REACTION; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; REACTION ANALYSIS; VIBRATION;

EID: 0032728463     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar950046a     Document Type: Article

References (39)

1. Levine, R. D.; Bernstein, R. B. Molecular Reaction Dynamics and Chemical Reactivity, Oxford University Press: New York, 1987.
2. 2O. J. Chem. Phys. 1998, 108, 4693-4696.
3. Crim, F. F. Bond-Selected Chemistry: Vibrational State Control of Photodissociation and Bimolecular Reaction. J. Phys. Chem. 1996, 100, 12725-12734.
4. Zare, R. N. Laser control of chemical reactions. Science 1998, 279, 1875-1879.
5. 2. J. Chem. Phys. 1990, 92, 6333.
6. Metz, R. B.; Thoemke, J. D.; Pfeiffer, J. M.; Crim, F. F. Selectively Breaking Either Bond in the Bimolecular Reaction of HOD with Hydrogen Atoms. J. Chem. Phys. 1993, 99, 1744-1751.
7. Sinha, A.; Hsiao, M. C.; Crim, F. F. Controlling Bimolecular Reactions: Mode and Bond Selected Reaction of Water with Hydrogen Atoms. J. Chem. Phys. 1991, 94, 4928.
8. Sinha, A.; Thoemke, J. D.; Crim, F. F. Controlling Bimolecular Reactions: Mode and Bond Selected Reaction of Water with Translationally Energetic Chlorine Atoms. J. Chem. Phys. 1992, 96, 372.
9. 2O and HOD. J. Phys. Chem. 1995, 99, 13748-13754.
10. Hsiao, M. C.; Sinha, A.; Crim, F. F. Energy Disposal in the Vibrational State-and Bond-Selected Reaction of Water with Hydrogen Atoms. J. Phys. Chem. 1991, 95, 8263.
11. Bronikowski, M. J.; Simpson, W. R.; Girard, B.; Zare, R. N. Bond-Specific Chemistry - OD-OH Product Ratios For the Reactions H+HOD(100) and H+HOD-(001). J. Chem. Phys. 1991, 95, 8647-8648. Bronikowski, M. J.; Simpson, W. R.; Zare, R. N. Effect of Reagent Vibration on the H+HOD Reaction-An Example of Bond-Specific Chemistry. J. Phys. Chem. 1993, 97, 2194-2203.
12. Bronikowski, M. J.; Simpson, W. R.; Girard, B.; Zare, R. N. Bond-Specific Chemistry - OD-OH Product Ratios For the Reactions H+HOD(100) and H+HOD-(001). J. Chem. Phys. 1991, 95, 8647-8648. Bronikowski, M. J.; Simpson, W. R.; Zare, R. N. Effect of Reagent Vibration on the H+HOD Reaction-An Example of Bond-Specific Chemistry. J. Phys. Chem. 1993, 97, 2194-2203.
13. 3 - State- to-State Differential Cross-Sections and Steric Effects For the HCl Product. J. Chem. Phys. 1995, 103, 7313-7335;
14. Pfeiffer, J. M.; Metz, R. B.; Thoemke, J. D.; Woods, E.; Crim, F. F. Reactions of O, H, and Cl atoms with Highly Vibrationally Excited HCN: Using Product States to Determine Mechanisms. J. Chem. Phys. 1996, 104, 4490-4501.
15. 3) → RH+CN(v,J) with R = Cl, H. J. Chem. Phys. 1996, 104, 4481-4489.
16. 3) → RH+CN(v,J) with R = Cl, H. J. Chem. Phys. 1996, 104, 4481-4489.
17. 2O (N, 0, 0). Chem. Phys. Lett. 1994, 217, 375-380.
18. Woods, E.; Cheatum, C. M.; Crim, F. F. Using Stretching and Bending Vibrations to Direct the Reaction of Cl Atoms with Isocyanic Acid (HNCO). J. Chem. Phys., in press.
19. Anderson, S. L. Mode-Selective Differential Scattering as a Probe of Polyatomic Ion Reaction Mechanisms. Acc. Chem. Res. 1997, 30, 28-36.
20. 4): Control of Product Branching by Hydrogen-bonded Complex Formation. J. Chem. Phys. 1998, 108, 2395-2407.
21. For example, see: Guettler, R. D.; Jones, G. C.; Posey, L. A.; Zare, R. N. Partial Control of an Ion-Molecule Reaction by Selection of the Internal Motion of the Polyatomic Reagent Ion. Science 1994, 266, 259-261.
22. Rosencwaig, A. Photoacoustics and Photacoustic Spectroscopy; Academic Press: New York, 1981.
23. -.
24. Child, M. S.; Halonen, L. Overtone Frequencies and Intensities in the Local Mode Picture. Adv. Chem. Phys. 1984, 57, 1-58.
25. 2. J. Phys. Chem. 1984, 88, 2971-2977.
26. Kudla, K.; Schatz, G. C. A Quasi-Classical Trajectory Study of Mode-Specific Reaction Dynamics in the Cl+HOD and H+HOD Reactions. Chem. Phys. 1993, 175, 71-82.
27. Schatz, G.; Wu, G.; Lendvay, G.; Fang, D.; Harding, L. Reaction of H with Highly Vibrationally Excited Water: Activated or Not? Faraday Discuss., in press.
28. 2+OH and Isotopes-Rotational Distributions and Cross Sections. J. Chem. Phys. 1993, 99, 7774-7786. Clary, D. C. Four-atom Reaction Dynamics. J. Phys. Chem. 1994, 98, 10678-10688. Nyman, G.; Clary, D. C. Vibrational and Rotational Effects in the Cl+HOD → HCl+OD Reaction. J. Chem. Phys. 1994, 100, 3556-3567.
29. 2+OH and Isotopes-Rotational Distributions and Cross Sections. J. Chem. Phys. 1993, 99, 7774-7786. Clary, D. C. Four-atom Reaction Dynamics. J. Phys. Chem. 1994, 98, 10678-10688. Nyman, G.; Clary, D. C. Vibrational and Rotational Effects in the Cl+HOD → HCl+OD Reaction. J. Chem. Phys. 1994, 100, 3556-3567.
30. 2+OH and Isotopes-Rotational Distributions and Cross Sections. J. Chem. Phys. 1993, 99, 7774-7786. Clary, D. C. Four-atom Reaction Dynamics. J. Phys. Chem. 1994, 98, 10678-10688. Nyman, G.; Clary, D. C. Vibrational and Rotational Effects in the Cl+HOD → HCl+OD Reaction. J. Chem. Phys. 1994, 100, 3556-3567.
31. 2O. J. Chem. Phys. 1993, 98, 6235-6247.
32. 2O. J. Chem. Phys. 1993, 98, 6235-6247.
33. The three quantum numbers designate the C-N stretch, the H-C-N bend, and the C-H stretch, respectively.
34. Harding, L. B. A theoretical study of reactions on the ClHCN surface. J. Phys. Chem. 1996, 100, 10123-10130.
35. Coffey, M.; Berghout, H.; Woods, E., III; Crim, F. Vibrational Spectroscopy and Intramolecular Energy Transfer In Isocyanic Acid (HNCO). J. Chem. Phys. 1999, 110, 10850-10862.
36. Kandel, S. A.; Zare, R. N. Reaction Dynamics of Atomic Chlorine with Methane: Importance of Methane Bending and Torsional Excitation in Controlling Reactivity. J. Chem. Phys. 1998, 109, 9719-9727.
37. 3: Watching Vibrational Energy Flow. J. Chem. Phys. 1997, 107, 661-664.
38. Raftery, D.; Iannone, M.; Phillips, C. M.; Hochstrasser, R. M. Hydrogen Abstraction Dynamics in Solution Studied By Picosecond Infrared-Spectroscopy. Chem. Phys. Lett. 1993, 201, 513-520. Raftery, D.; Gooding, E.; Romanovsky, A.; Hochstrasser, R. M. Vibrational Product State Dynamics in Solution-Phase Bimolecular Reactions-Transient Infrared Study of CN Radical Reactions. J. Chem. Phys. 1994, 101, 8572-8579.
39. Raftery, D.; Iannone, M.; Phillips, C. M.; Hochstrasser, R. M. Hydrogen Abstraction Dynamics in Solution Studied By Picosecond Infrared-Spectroscopy. Chem. Phys. Lett. 1993, 201, 513-520. Raftery, D.; Gooding, E.; Romanovsky, A.; Hochstrasser, R. M. Vibrational Product State Dynamics in Solution-Phase Bimolecular Reactions-Transient Infrared Study of CN Radical Reactions. J. Chem. Phys. 1994, 101, 8572-8579.