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Volumn 122, Issue 10, 2005, Pages

Imaging a reactive resonance in the Cl+ CH4 reaction

Author keywords

[No Author keywords available]

Indexed keywords

ADIABATIC BARRIER; ENERGY FLOW; MOLECULAR REACTIONS; POTENTIAL ENERGY SURFACE;

EID: 17444377542     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1871894     Document Type: Article
Times cited : (96)

References (32)
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    • J. C. Polanyi, Science 0036-8075 236, 680 (1987); J. C. Polanyi, Acc. Chem. Res. 5, 161 (1972).
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    • Polanyi, J.C.1
  • 3
    • 0001478448 scopus 로고
    • J. C. Polanyi, Science 0036-8075 236, 680 (1987); J. C. Polanyi, Acc. Chem. Res. 5, 161 (1972).
    • (1972) Acc. Chem. Res. , vol.5 , pp. 161
    • Polanyi, J.C.1
  • 7
    • 0002804631 scopus 로고    scopus 로고
    • Negative ion photodetachment spectroscopy is an elegant and powerful probe of transition state structure. Using this half-collision approach, the first reactive resonance was detected in IHI-. See D. M. Neumark, PhysChemComm 5, 76 (2002) for the most recent review.
    • (2002) PhysChemComm , vol.5 , pp. 76
    • Neumark, D.M.1
  • 10
    • 0041765733 scopus 로고    scopus 로고
    • 0021-9606 10.1063/1.1582172
    • S. D. Chao and R. T. Skodje, J. Chem. Phys. 0021-9606 10.1063/1.1582172 119, 1462 (2003); S. D. Chao and R. T. Skodje, Theor. Chem. Acc. 108, 273 (2002).
    • (2003) J. Chem. Phys. , vol.119 , pp. 1462
    • Chao, S.D.1    Skodje, R.T.2
  • 11
    • 0036027247 scopus 로고    scopus 로고
    • S. D. Chao and R. T. Skodje, J. Chem. Phys. 0021-9606 10.1063/1.1582172 119, 1462 (2003); S. D. Chao and R. T. Skodje, Theor. Chem. Acc. 108, 273 (2002).
    • (2002) Theor. Chem. Acc. , vol.108 , pp. 273
    • Chao, S.D.1    Skodje, R.T.2
  • 26
    • 17444384519 scopus 로고    scopus 로고
    • To be more precise, we believe that the ridge observed here actually comprises two types: a rapidly evolving resonance ridge spanned over a narrow energy range near threshold as the one in Fig. 2 of Ref. 7b, which overlaps with a direct, transition-state ridge extended over a much wider energy range as the ground state pair.
    • To be more precise, we believe that the ridge observed here actually comprises two types: a rapidly evolving resonance ridge spanned over a narrow energy range near threshold as the one in Fig. 2 of Ref., which overlaps with a direct, transition-state ridge extended over a much wider energy range as the ground state pair.
  • 27
    • 17444396312 scopus 로고    scopus 로고
    • note
    • The vibrationally adiabatic curves depicted in Fig. correspond to zero impact parameter reaction. For larger impact parameter collisions, those curves, so as the resonance state, will shift upward in energy due to the centrifugal effects.
  • 28
    • 0027971670 scopus 로고
    • W. L. Hase, Science 266, 998 (1994).
    • (1994) Science , vol.266 , pp. 998
    • Hase, W.L.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.