How biogenic terpenes govern the correlation between sulfuric acid concentrations and new particles formation

Journal of Geophysical Research Atmospheres

Volumn 113, Issue 12, 2008, Pages

  Bonn, B ^a,b   Kulmala, M ^a   Riipinen, I ^a   Sihto, S L ^a   Ruuskanen, T M ^a  

^a UNIVERSITY OF HELSINKI   (Finland)

^b GOETHE UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; ATMOSPHERIC COMPOSITION; HYDROCARBONS; NUCLEATION; SULFURIC ACID; WATER VAPOR;

AEROSOL FORMATION; CHEMICAL COMPOSITION; NUCLEATION; SULFURIC ACID; TERPENE;

EURASIA; EUROPE; FINLAND; HYYTIALA; LANSI SUOMEN; NORTHERN EUROPE; SCANDINAVIA;

EID: 50049135899     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2007JD009327     Document Type: Article

References (46)

1. Bonn, B. (2002), Bestimmung der Größenverteilung von sekundären organischen Aerosolen aus der Photooxidation biogener Terpene, Ph.D. thesis, Mainz Univ., Mainz, Germany.
2. Bonn, B., and G. K. Moortgat (2003), Sesquiterpene ozonolysis: Origin of atmospheric new particle formation from biogenic hydrocarbons, Geophys. Res. Lett., 30(11), 1585, doi:10.1029/2003GL017000.
3. Bonn, B., G. Schuster, and G. K. Moortgat (2002), Influence of water vapor on the process of new particle formation during monoterpene ozonolysis, J. Phys. Chem. A, 106, 2869-2881.
4. Bonn, B., A. Hirsikko, H. Hakola, T. Kurtén, L. Laakso, M. Boy, M. Dal Maso, J. M. Mäkelä, and M. Kulmala (2007a), Ambient sesquiterpene concentration and its link to air ion measurements, Atmos. Chem. Phys., 7, 2893-2916.
5. Bonn, B., H. Korhonen, T. Petd̈jä, M. Boy, and M. Kulmala (2007b), Understanding the formation of biogenic secondary organic aerosol from alpha-pinene in smog chamber studies: Contribution of organic peroxy radicals, Atmos. Chem. Phys. Discuss., 7, 3901-3939.
6. Boy, M., et al. (2005), Sulphuric acid closure and contribution to nucleation mode particle growth, Atmos. Chem. Phys., 5, 863-878.
7. Chuong, B., J. Zhang, and N. M. Donahue (2004), Cycloalkene ozonolysis: Collisionally mediated mechanistic branching, J. Am. Chem. Soc., 126, 12,363-12,373.
8. Clement, C. F., L. Pirjola, M. Dal Maso, J. M. Mäkelä, and M. Kulmala (2001), Analysis of particle formation bursts observed in Finland, J. Aerosol Sci., 32, 217-236.
9. Criegee, R. (1975), Mechanismus der Ozonolyse, Angew. Chem., 87, 765-771.
10. Dal Maso, M., M. Kulmala, I. Riipinen, R. Wagner, T. Hussein, P. P. Aalto, and K. E. J. Lehtinen (2005), Formation and growth of fresh atmospheric aerosols: Eight years of aerosol size distribution data from SMEAR II, Hyytiälä, Boreal Environ. Res., 5, 323-336.
11. Finlayson-Pitts, B., and J. N. Pitts (2000), Chemistry of the Upper and Lower Atmosphere, 2nd ed., Academic, New York.
12. Finlayson-Pitts, B. J., T. T. H. Pham, C. C. Lai, S. N. Johnson, L. L. Lucio-Gough, J. Mestas, and D. Iwig (1998), Thermal decomposition of phospholipid secondary ozonides: Implications for the toxity of inhaled ozone, Inhalation Toxicol., 10, 813-830.
13. Friedlander, S. K. (2000), Smoke, Dust, and Haze, 2nd ed., Oxford Univ. Press, New York.
14. Großmann, D. (1999), Die Gasphasenozonolyse von Alkenen in Gegenwart von Wasserdampf als Quelle für Wasserstoffperoxid und organische Peroxide in der Atmosphdre, Ph.D. thesis, Mainz Univ., Mainz, Germany.
15. Guenther, A., et al. (1995), A global model of natural volatile organic compound emissions, J. Geophys. Res., 100(D5), 8873-8892.
16. Guenther, A., T. Karl, P. Harley, C. Wiedinmyer, P. I. Palmer, and C. Geron (2006), Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmos. Chem. Phys., 6, 3181-3210.
17. Hakola, H., V. Tarvainen, T. Laurila, V. Hiltunen, H. Hellén, and P. Keronen (2003), Seasonal variation of VOC concentrations above a boreal coniferous forest, Atmos. Environ., 37, 1623-1637.
18. Hakola, H., V. Tarvainen, J. Bäck, H. Ranta, B. Bonn, J. Rinne, and M. Kulmala (2006), Seasonal variation of mono- and sesquiterpene emission rates of Scots pine, Biogeosciences, 2, 93-101.
19. Hari, P., and M. Kulmala (2005), Station for Measuring Ecosystem-Atmosphere Relations (SMEAR II), Boreal Environ. Res., 10, 315-322.
20. Hirsikko, A., L. Laakso, U. Hörrak, P. Aalto, V.-M. Kerminen, and M. Kulmala (2005), Annual and size dependent variation of growth rates and ion concentrations in boreal forest, Boreal Environ. Res., 10, 357-370.
21. Hoffmann, T. (Ed.) (2002), Origin and formation of secondary organic aerosol (OSOA), final report, EU project, Eur. Union, Brussels,
22. Joback, K. G., and R. C. Reid (1987), Estimation of pure-component properties from group contributions, Chem. Eng. Commun., 57, 233-243.
23. Kerminen, V.-M., and M. Kulmala (2002), Analytical formulae connecting the 'real' and the 'apparent' nucleation rate and the nuclei number concentration for atmospheric nucleation events, J. Aerosol Sci., 33, 609-622.
24. Kilpatrick, W. D. (1971), An experimental mass-mobility relation for ions in the air at atmospheric pressure, Proc. Annu. Conf Massspectrose., 19, 320-325.
25. Kulmala, M., L. Pirjola, and J. M. Mäkelä (2000), Stable sulphate clusters as a source of new atmospheric particles, Nature, 404, 37-39.
26. Kulmala, M., et al. (2001a), Overview of the international project on biogenic aerosol formation in the boreal forest (BIOFOR), Tellus, Ser. B, 53, 324-343.
27. Kulmala, M., M. Dal Maso, J. M. Mäkelä, L. Pirjola, M. Väkevä, P. Aalto, P. Miikkulainen, K. Hämeri, and C. D. O'Dowd (2001b), On the formation, growth and composition of nucleation mode particles, Tellus, Ser B, 53, 479-490.
28. Kulmala, M., V.-M. Kerminen, T. Anttila, A. Laaksonen, and C. O'Dowd (2004a), Organic aerosol formation via sulphate cluster activation, J. Geophys. Res., 109, D04205, doi:10.1029/2003JD003961.
29. Kulmala, M., L. Laakso, K. E. J. Lehtinen, I. Riipinen, M. Dal Maso, T. Anttila, V.-M. Kerminen, U. Hõrrak, M. Vana, and H. Tammet (2004b), Initial steps of aerosol growth, Atmos. Phys. Chem., 4, 2553-2560.
30. Kulmala, M., H. Vehkamäki, T. Petäjä, M. Dal Maso, A. Lauri, V.-M. Kerminen, W. Birmili, and P. H. McMurry (2004c), Formation and growth rates of ultrafine atmospheric particles: A review of observations, J. Aerosol Sci., 35, 143-176.
31. Kulmala, M., K. E. J. Lehtinen, and A. Laaksonen (2006), Cluster activation theory as an explanation of the linear dependence between formation rate of 3 nm particles and sulphuric acid concentration, Atmos. Chem. Phys., 6, 787-793.
32. Kulmala, M., et al. (2007a), The condensation particle counter battery (CPCB): A new tool to investigate the activation properties of nanoparticles, J. Aerosol Sci., 38, 289-304.
33. Kulmala, M., et al. (2007b), Towards direct measurements of atmospheric nucleation, Science, 318, 89-92.
34. Kurtén, T., B. Bonn, H. Vehkamäki, and M. Kulmala (2007), Computational study of the reaction between biogenic stabilized Criegee intermediates and sulphuric acid, J. Phys. Chem. A, 111, 3394-3401.
35. Laakso, L., T. Anttila, K. E. J. Lehtinen, P. P. Aalto, M. Kulmala, U. Hõrrak, H. Tammet, and J. Joutsensaari (2004), Kinetic nucleation and ions in boreal particle formation events, Atmos. Chem. Phys., 4, 2353-2366.
36. Lehtinen, K. E. J., and M. Kulmala (2003), A model for particle formation and growth in the atmosphere with molecular resolution in size, Atmos. Chem. Phys., 2, 251-257.
37. Loreto, F., M. Mannozzi, C. Maris, P. Nascetti, F. Ferranti, and S. Pasqualini (2001), Ozone quenching properties of isoprene and its antioxidant role in leaves, Plant Phys., 126, 993-1000.
38. Pirjola, L., M. Kulmala, M. Wilck, A. Bischoff, F. Stratmann, and E. Otto (1999), Formation of sulphuric acid aerosols and cloud condensation nuclei: An expression for significant nucleation and model comparison, J. Aerosol Sci., 30, 1079-1094.
39. Riipinen, L, et al. (2007), Connections between atmospheric sulphuric acid and new particle formation during QUEST III-IV campaigns in Heidelberg and Hyytiälä, Atmos. Chem. Phys., 7, 1899-1914.
40. Rinne, J., T.-M. Ruuskanen, A. Reissell, R. Taipale, H. Hakola, and M. Kulmala (2005), Online PTR-MS measurements of atmospheric concentrations of volatile organic compounds in a European boreal forest ecosystem, Boreal Environ. Res., 5, 425-436.
41. Seinfeld, J. H., and S. N. Pandis (1998), Atmospheric Chemistry and Physics, Wiley Intersci., New York.
42. Shu, Y., and R. Atkinson (1994), Rate constants for the gas-phase reactions of O3 with a series of terpenes and OH radical formation from the O3 reactions with sesquiterpenes at 296 ± 2K, Int. J. Chem. Kinet., 26, 1193-1205.
43. Sihto, S.-L., et al. (2006), Atmospheric sulphuric acid and aerosol formation: Implications from atmospheric measurements for nucleation and early growth mechanisms, Atmos. Chem. Phys., 6, 4079-4091.
44. Spracklen, D. V., K. J. Pringle, K. S. Carslaw, M. P. Chipperfield, and G. W. Mann (2005), A global off-line model of size-resolved aerosol microphysics: I. Model development and prediction of aerosol properties, Atmos. Chem. Phys., 5, 2227-2252.
45. Spracklen, D. V, K. S. Carslaw, M. Kulmala, V.-M. Kerminen, G. W. Mann, and S.-L. Sihto (2006), The contribution of boundary layer nucleation venets to total particle concentrations on regional and global scales, Atmos. Chem. Phys., 6, 5631-5648.
46. Weber, R. J., P. H. McMurry, R. L. Mauldin III, D. Tanner, F. L. Eisele, A. D. Clarke, and V. N. Kapustin (1999), New particle formation in the remote troposphere: A comparison of observations at various sites, Geophys. Res. Lett., 26, 307-310.