Sesquiterpene ozonolysis: Origin of atmospheric new particle formation from biogenic hydrocarbons

Geophysical Research Letters

Volumn 30, Issue 11, 2003, Pages

  Bonn, Boris ^a   Moortgat, Geert K ^a  

^a MAX PLANCK INSTITUTE FOR CHEMISTRY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOLS; NUCLEATION; OXIDATION; VAPORS;

NON-VOLATILE ORGANICS;

GEOPHYSICS;

AEROSOL; ATMOSPHERIC PARTICLE; BIOGENIC EMISSION; HYDROCARBON; MONOTERPENE; NUCLEATION; OXIDATION;

EID: 0041409795     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/2003GL017000     Document Type: Article

References (30)

1. Andreae, M. O., and P. J. Crutzen, Biogeochemical sources and role in atmospheric chemistry, Science, 276, 1052-1058, 1997.
2. Andersson-Sköld, Y., and D. Simpson, Secondary organic aerosol formation in northern Europe: A model study, J Geophys. Res, 106, 7357-7374, 2001.
3. Asher, W. E., J. F. Pankow, G. B. Erdakos, and J. H. Seinfeld, Estimating the vapor pressures of multi-functional oxygen-containing organic compounds using group contribution methods, Atmos. Environ., 36, 1483-1498, 2002.
4. Atkinson, R., Gas-phase tropospheric chemistry of volatile organic compounds: 1. Alkanes and alkenes, J. Phys. Chem. Ref. Data, 26, 215-290, 1997.
5. Bonn, B., G. Schuster, and G. K. Moortgat, Influence of water vapor on the process of new particle formation during monoterpene ozonolysis, J. Phys. Chem. A, 106, 2869-2881, 2002.
6. 3, and the influence of water vapour: Particle size distribution studies, Atmos. Chem. Phys., 2, 183-196, 2002.
7. Boy, M., and M. Kulmala, Nucleation events in the continental boundary layer: Influence of physical and meteorological parameters, Atmos. Chem. Phys., 2, 1-16, 2002.
8. Calvert, J. G., R. Atkinson, J. A. Kerr, S. Madronich, G. K. Moortgat, and T. Wallington, Mechanisms of atmospheric oxidation of alkenes, Oxford Univ. Press, Oxford, 2000.
9. Ciccioli, P., E. Brancaleoni, M. Frattoni, V. Di Palo, R. Valentini, G. Tirone, G. Seufert, N. Berlin, U. Hansen, O. Csiky, R. Lenz, and M. Sharma, Emission of reactive terpene compounds from orange orchards and their removal by within-canopy processes, J. Geophys. Res., 104, 8077-8094, 1999.
10. Fuentes, J. D., M. Lerdau, R. Atkinson, D. Baldocchi, J. W. Bottenheim, P. Ciccioli, B. Lamb, C. Geron, L. Gu, A. Guenther, T. D. Sharkey, and W. Stockwell, Biogenic hydrocarbons in the atmospheric boundary layer: A review, Bull. Am. Meteorol. Soc., 81, 1527-1575, 2000.
11. Griffin, R. J., D. R. Cocker, J. H. Seinfeld, and D. Dabdub, Estimate of global atmospheric organic aerosol from biogenic hydrocarbons, Geophys. Res. Lett., 26, 2721-2723, 1999.
12. Hakola, H., T. Laurila, J. Rinne, and K. Puhto, The ambient concentrations of biogenic hydrocarbons at a northern European, boreal site, Atmos. Environ., 34, 4971-4982, 2000.
13. Hakola, H., T. Laurila, V. Lindfors, H. Hellen, A. Gaman, and J. Rinne, Variation of VOC emission rates of birch species during growing season, Boreal Env. Res., 6, 237-249, 2001.
14. Harrison, D., M. C. Hunter, A. C. Lewis, P. W. Seakins, B. Bonsang, V. Gros, M. Kanakidou, M. Touaty, I. Kavouras, N. Mihalopoulos, E. Stephanou, C. Alves, T. Nunes, and C. Pio, Ambient isoprene and monoterpene concentrations in a Greek fir (abies borisii-regis) forest. Reconciliation with emissions measurements and effects on measured OH concentrations, Atmos. Environ., 35, 4699-4711, 2001.
15. Hoffmann, Th., J. Odum, F. Bowman, D. Collins, D. Klockow, R. C. Flagan, and J. H. Seinfeld, Formation of organic aerosols from the oxidation of biogenic hydrocarbons, J. Atmos. Chem., 26, 189-222, 1997.
16. Kanakidou, M., K. Tsigaridis, F. J. Dentener, and P. J. Crutzen, Human-activity-enhanced formation of organic aerosols by biogenic hydrocarbon oxidation, J. Geophys. Res., 105, 9243-9254, 2000.
17. Kavouras, I. G., N. Mihalopoulos, and E. G. Stephanou, Formation of atmospheric particles from organic acids produced by forests, Nature, 395, 683-686, 1998.
18. Kavouras, I. G., and E. G. Stephanou, Direct evidence of atmospheric secondary organic aerosol formation in forest atmosphere through heteromolecular nucleation, Environ. Sci. Technol., 36, 5083-5091, 2002.
19. Kerminen, V., A. Virkkula, R. Hillamo, A. S. Wexler, and M. Kulmala, Secondary organics and atmospheric cloud condensation nuclei production, J. Geophys. Res., 105, 9255-9264, 2000.
20. Kirchstetter, T. W., T. Novakov, R. Morales, and O. Rosario, Differences in the volatility of organic aerosols in unpolluted tropical and polluted continental atmospheres, J. Geophys. Res., 105, 26,547-26,554, 2000.
21. Koch, St., R. Winterhalter, E. Uherek, A. Kolloff, P. Neeb, and G. K. Moortgat, Formation of new particles in the gas-phase ozonolysis of monoterpenes, Atmos. Environ., 34, 4031-4042, 2000.
22. Kulmala, M., L. Pirjola, and J. M. Mäkelä, Stable sulphate clusters as a source of new atmospheric particles, Nature, 404, 66-69, 2000.
23. Leaitch, W. R., J. W. Bottenheim, T. A. Biesenthal, S.-M. Li, P. S. K. Liu, K. Asalian, H. Dryfhout-Clark, F. Hopper, and F. Brechtel, A case study of gas-to-particle conversion in an eastern canadian forest, J. Geophys. Res., 104, 8095-8111, 1999.
24. Mäkelä, J. M., P. Aalto, V. Jokinen, T. Pohja, A. Nissinen, S. Palmroth, T. Markkanen, K. Seitsonen, H. Lihavainen, and M. Kulmala, Observations of ultrafine aerosol particle formation and growth in boreal forest, Geophys. Res. Lett., 24, 1219-1222, 1997.
25. Pöschl, U., R. von Kuhlmann, N. Poisson, and P. J. Crutzen, Development and intercomparison of condensed isoprene oxidation mechanisms for global atmospheric modeling, J. Atmos. Chem., 37, 29-52, 2000.
26. Pruppacher, H. R., and J. D. Klett, Microphysics of clouds and precipitation. Kluwer, Dordrecht, 1997.
27. Seinfeld, J. H., and S. N. Pandis, Atmospheric chemistry and physics, Wiley Interscience, New York, 1998.
28. 3 reactions with sesquiterpenes at 296 ± 2 K, Int. J. Chem. Kinet., 26, 1193-1205, 1994.
29. Went, F. W., Blue haze in the atmosphere, Nature, 187, 641-645, 1960.
30. Yu, J., R. C. Flagan, and J. H. Seinfeld, Identification of products containing -COOH, -OH, and -C = O in atmospheric oxidation of hydrocarbons, Environ. Sci. Technol., 32, 2357-2370, 1998.