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FeII4FeIII4(m-CN) 12(tp)8]·12DMF·2Et2O· 4H2O (1, C128H192N72B 8Fe8 O18, M, 3560.67, monoclinic, P21/c, a, 17.983(4) Å, b, 32.249(7) Å, c, 17.424(4) Å, b, 109.347(4)°, V, 9534(4) Å3, Z, 2, T, 200 K, r calcd, 1.240 g/cm3, μ, 0.664 mm-1, F(000, 3703, 41 870 reflections collected, λ, 0.710 73 Å, 1081 parameters for 13 688 independent reflections with I > 2σ gave R1, 0.0764 and wR2, 0.2165. Anal. Calcd for C84H 80N60B8Fe8·4DMF· 3H2O dried sample, C, 41.04; H, 4.09; N, 31.91. Found: C, 40.90; H, 4.06; N, 31.72
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2O (dried sample): C, 41.04; H, 4.09; N, 31.91. Found: C, 40.90; H, 4.06; N, 31.72.
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16
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48649084353
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Mössbauer parameters are calculated relative to the metal iron
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Mössbauer parameters are calculated relative to the metal iron.
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