Reversible photoinduced magnetic properties in the heptanuclear complex [MoIV(CN)2(CN-CuL)6]8+: A photomagnetic high-spin molecule

Angewandte Chemie - International Edition

Volumn 43, Issue 41, 2004, Pages 5468-5471

  Herrera, Juan Manuel ^a   Marvaud, Valérie ^a   Verdaguer, Michel ^a   Marrot, Jérôme ^c   Kalisz, Marguerite ^b   Mathonlère, Corine ^b  

^a CNRS   (France)

^b INST CHIM MATIERE COND BORDEAUX   (France)

^c UNIVERSITÉ DE VERSAILLES SAINT QUENTIN EN YVELINES   (France)

Author keywords

Cyanides; Electron transfer; Heterometallic complexes; Magnetic properties; Photochemistry

Indexed keywords

COPPER; ELECTRIC EXCITATION; ELECTRON TRANSITIONS; MOLYBDENUM COMPOUNDS;

METASTABLE; THERMALLY REVERSIBLE;

MAGNETIC PROPERTIES;

AMINE; COPPER COMPLEX; CYANIDE; FERRIC FERROCYANIDE; MOLYBDENUM COMPLEX; TRIS(2 AMINOMETHYL)AMINE; UNCLASSIFIED DRUG;

ANISOTROPY; ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; ELECTRON TRANSPORT; MAGNETISM; NEUTRON DIFFRACTION; PHOTOCHEMISTRY; REACTION ANALYSIS; SPIN TRAPPING; TEMPERATURE DEPENDENCE; ULTRAVIOLET SPECTROSCOPY;

COPPER; CRYSTALLOGRAPHY, X-RAY; LIGHT; MAGNETICS; MODELS, MOLECULAR; MOLYBDENUM; ORGANOMETALLIC COMPOUNDS; PHOTOCHEMISTRY; TEMPERATURE; TIME FACTORS;

EID: 8544249181     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460387     Document Type: Article

References (41)

1. a) A. P. de Silva, N. D. McClenaghan, Chem. Eur. J. 2004, 10, 574-586;
2. b) R. L. Carroll, C. B. German, Angew. Chem. 2002, 114, 4556-4579; Angew. Chem. Int. Ed. 2002, 41, 4378-4400.
3. b) R. L. Carroll, C. B. German, Angew. Chem. 2002, 114, 4556-4579; Angew. Chem. Int. Ed. 2002, 41, 4378-4400.
4. a) Guest Editor: M. Irie, Chem. Rev. 2000, 100, 1683-1890;
5. b) V. Balzani, L. Moggi, F. Scandola, Supramolecular Photochemistry (Ed.: V. Balzani), D. Reidel, Dordrecht, The Netherlands, 1987, pp. 1-28.
6. a) O. Kahn, Molecular Magnetism, Wiley-VCH, Weinheim, 1993;
7. b) "Molecular Magnetism: from molecular assemblies to the devices": NATO Sci. Ser. 11 1995, 321;
8. c) Magnetism: molecules to materials (Eds.: J. S. Miller, M. Drillon), Wiley-VCH, Weinheim, 2001.
9. a) O. Sato, Acc. Chem. Res. 2003, 36, 692-700, and references therein;
10. b) P. Gütlich, Y. Garcia, T. Woike, Coord. Chem. Rev. 2001, 219-221, 839-879.
11. a) P. Gütlich, A. Hauser, H. Spiering, Angew. Chem. 1994, 106, 2109-2141; Angew. Chem. Int. Ed. Engl. 1994, 33, 2024-2054;
12. a) P. Gütlich, A. Hauser, H. Spiering, Angew. Chem. 1994, 106, 2109-2141; Angew. Chem. Int. Ed. Engl. 1994, 33, 2024-2054;
13. b) P. Gütlich, A. Hauser, Coord. Chem. Rev. 1990, 97, 1;
14. c) S. Decurtins, P. Gütlich, CP. Köhler, H. Spiering, A. Hauser, Chem. Phys. Lett. 1984, 105, 1-4.
15. Y. Teki, S. Miyamoto, M. Nakatsuji, Y. Miura, J. Am. Chem. Soc. 2001, 123, 294-305.
16. K. Takayama, K. Matsuda, M. Irie, Chem. Eur. J. 2003, 9, 5605-5609.
17. a) O. Sato, T. Iyoda, A. Fujishima, K. Hashimoto, Science, 1996, 272, 704;
18. b) M. Verdaguer, Science 1996, 272, 698;
19. c) A. Bleuzen, C. Lomenech, V. Escax, F. Villain, F. Varret, C. Cartier dit Moulin, M. Verdaguer, J. Am. Chem. Soc. 2000, 122, 6648-6652;
20. d) N. Shimamoto, S.-I. Ohkoshi, O. Sato, K. Hashimoto, Inorg. Chem. 2002, 41, 678-684.
21. a) M.-L. Boulot, C. Roux, J.-P. Audière, A. Dausse, J. Zarembowitch, Inorg. Chem. 1996, 35, 3975-3980;
22. b) M.-L. Boillot, S. Chantraine, J. Zarembowitch, J.-Y. Lallemand, J. Prunet, New J. Chem. 1999, 23, 179-183.
23. a) S.-I Ohkoshi, N. Machida, J. Z. Zhong, K. Hashimoto, Synth. Met. 2001, 122, 523-527;
24. b) Y. Arimoto, S.-I. Ohkoshi, J. Z. Zhong, H. Seino, Y. Mizobe, K. Hashimoto, J. Am. Chem. Soc. 2003, 125, 9240-9241.
25. B. Sieklucka, Prog. React. Kinet. Mech. 1999, 24, 165-221, and references therein.
26. G. Rombaut, M. Vereist, S. Golhen, L. Ouahab, C. Mathonière, O. Kahn, Inorg. Chem. 2001, 40, 1151-1159.
27. a) V. Marvaud, C. Decroix, A. Souiller, C. Guyard-Duhayon, J. Vaissermann, F. Gonnet, M. Verdaguer, Chem. Eur. J. 2003, 9, 1677-1691;
28. b) V. Marvaud, C. Decroix, A. Scuiller, F. Tuyéras, C. Guyard-Duhayon, J. Vaissermann, J. Marrot, F. Gonnet, M. Verdaguer, Chem. Eur. J. 2003, 9, 1692-1705.
29. a) G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull. 2000, 25, 66-71, and references therein;
30. b) "Molecular Cluster Magnets": J. R Long in Chemistry of Nanostructural Materials (Ed.: P. Yang), World scientific, Hong Kong, 2003, pp. 291-315, and references therein;
31. c) D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278-309; Angew. Chem. Int. Ed. 2003, 42, 268-297.
32. c) D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278-309; Angew. Chem. Int. Ed. 2003, 42, 268-297.
33. a) T. Mallah, C. Auberger, M. Verdaguer, P. Veillet, J. Chem. Soc. Chem. Commun. 1995, 61-62;
34. b) A. Scuiller, T. Mallah, M. Verdaguer, J.-L. Tholence, P. Veillet, New J. Chem. 1996, 20, 1-4.
35. M. F. A. Hendrickx, V. S. Mironov, L. F. Chibotaru, A. Ceulemans. Inorg. Chem. 2004, 43, 3142-3150, and references therein.
36. a) M. V. Bennett, J. R. Long, J. Am. Chem. Soc. 2003, 125, 2394-2395;
37. b) M. P. Shores, J. J. Sokol, J. R. Long, J. Am. Chem. Soc. 2002,124, 2279-2292;
38. c) J. J. Sokol, A. Hee, J. R. Long, J. Am. Chem. Soc. 2002,124, 7656-7657.
39. a) G. M. Sheldrick, SADABS, Program for Scaling and Correction of Area Detector Data, University of Göttingen, Göttingen (Germany), 1997;
40. b) R. H. Blessing, Acta Crystallogr. Sect. A 1995, 51, 33.
41. G. M. Sheldrick, SHELX-TL, Version 6.14, University of Göttingen, Bruker AXS Inc., Madison, WI, 2003.