Raising the Spin-Reversal Barrier in Cyano-Bridged Single-Molecule Magnets: Linear MnIII2MIII(CN)6 (M = Cr, Fe) Species Incorporating [(5-Brsalen)Mn]+ Units

Inorganic Chemistry

Volumn 43, Issue 5, 2004, Pages 1606-1608

  Choi, Hye Jin ^a   Sokol, Jennifer J ^a   Long, Jeffrey R ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

5 N,N' ETHYLENEBIS(5 BROMOSALICYLIDENE)AMINATO DIANION; ANION; CHROMIUM DERIVATIVE; CYANIDE; IRON DERIVATIVE; MANGANESE DERIVATIVE; METHANOL; UNCLASSIFIED DRUG; WATER;

ARTICLE; CRYSTAL STRUCTURE; LOW TEMPERATURE PROCEDURES; MAGNET; MOLECULAR INTERACTION; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 1542347648     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic035327q     Document Type: Article

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34. 8: C, 35.72; H, 2.53; N, 10.97. Found: C, 35.98; H, 2.52; N, 10.86. The X-ray powder diffraction pattern for this compound matches that simulated from its crystal structure.13
35. 8: C, 35.62; H, 2.52; N, 10.93. Found: C, 35.47; H, 2.46; N, 10.93. The X-ray powder diffraction pattern for this compound matches that simulated from its crystal structure.13
36. 2 = 0.0994. Data were collected using graphite monochromated Mo Kα radiation, and corrected for Lorentz, polarization, and absorption effects. The structures were refined against all data using SHELXTL 5.0.
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38. III center into account, and is therefore only approximate.