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Volumn 47, Issue 13, 2008, Pages 5831-5840

Sn12O8(OH)4(OEt)28(HOEt) 4: An additional member in the family of dodecameric oxo clusters

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EID: 47949103115     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic800123z     Document Type: Article
Times cited : (18)

References (78)
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    • (2004) Comprehensive Coordination Chemistry II , pp. 635-678
    • Pope, M.T.1
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    • Hill, C.L.1
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    • (b) Christou, G. Polyhedron 2005, 24, 2065-2075.
    • (2005) Polyhedron , vol.24 , pp. 2065-2075
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    • Verdenelli, M.; Parola, S.; Hubert-Pfalzgraf, L. G.; Lecocq, S. Polyhedron 2000, 19, 20692075.
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    • 119Sn NMR spectra of the solutions from which the crystals grow gave little clue on the species present. These spectra consist of one intense and broad resonance at -615 ppm and two minor ones at -606 and -609 ppm. These resonances correspond to six-coordinate tin atoms, and the major one might be related to a trimer with the formula Sn3(μ3-O, μ2-OEt)3(OEt)7(HOEt)2, similar to the one described in ref 11. Similarly, the hydrolysis of [Sn(O iPr)4·(HOiPr)]2 in THF (H2O/Sn, 0.5) yields a solution, the 119Sn NMR spectrum of which consists of a unique resonance, at -595 ppm, flanked by a pair of coupling satellites [2J(119Sn-117Sn, 225 Hz] with intensities corresponding to those of a trimer. This compound could not be isolated but likely corresponds to Sn3μ3-O, μ
    • 2.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.