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For examples of electronic effects in P-C bond scission reactions, see: (a) Dubois, R. A.; Garrou, P. E. Organometallics 1986, 5, 466. (b) Abatjoglou, A. G.; Bryant, D. R. Organometallics 1984, 3, 932.
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5344264018
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note
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pc) associated with the suggested decomposition product(s). Moreover, if the decomposition of the dianion was the predominant pathway, one would not expect to see the current ratio of near unity that we find with the first reduction step (Figure 2a).
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5344239174
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note
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1/2), which is characteristic of this genre of cluster (see refs 13b and 22).
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5344279356
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note
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-1 found in the maleic anhydride ring. This indicates that the maleic ring is not the predominant site of reduction.
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42
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0000957070
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(b) Cf.: Yang, K.; Bott, S. G.; Richmond, M. G. Organometallics 1995, 14, 2387.
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5344250135
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note
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Due the problematic nature in determining the percent yield in such a cluster fragmentation reaction, we have only reported the weight amount of isolated material.
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