Reversible thermal activation of a triphenylphosphine P-C bond on a cationic non-hydridic triruthenium carbonyl cluster complex. Structural characterization of a μ-η1:η2-benzoyl derivative

Organometallics

Volumn 16, Issue 8, 1997, Pages 1743-1748

  Cabeza, Javier A ^a   Del Río, Ignacio ^a   Riera, Víctor ^a   García Granda, Santiago ^a   Sanni, S Bamidele ^a,b  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITY OF BENIN   (Nigeria)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000422937     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om961046x     Document Type: Article

References (58)

1. See, for example: (a) The Chemistry of Metal Cluster Complexes; Shriver, D. F., Kaesz, H. D., Adams, R. D., Eds.; VCH Publishers: New York, 1990. (b) Mingos, D. M. P.; Wales, D. J. Introduction to Cluster Chemistry; Prentice-Hall International: Englewood Cliffs, NJ, 1990. (c) Metal Clusters; Moskovits, M., Ed.; John Wiley & Sons: New York, 1986. (d) Transition Metal Clusters; Johnson, B. F. G., Ed.; John Wiley & Sons: New York, 1980.
2. See, for example: (a) The Chemistry of Metal Cluster Complexes; Shriver, D. F., Kaesz, H. D., Adams, R. D., Eds.; VCH Publishers: New York, 1990. (b) Mingos, D. M. P.; Wales, D. J. Introduction to Cluster Chemistry; Prentice-Hall International: Englewood Cliffs, NJ, 1990. (c) Metal Clusters; Moskovits, M., Ed.; John Wiley & Sons: New York, 1986. (d) Transition Metal Clusters; Johnson, B. F. G., Ed.; John Wiley & Sons: New York, 1980.
3. See, for example: (a) The Chemistry of Metal Cluster Complexes; Shriver, D. F., Kaesz, H. D., Adams, R. D., Eds.; VCH Publishers: New York, 1990. (b) Mingos, D. M. P.; Wales, D. J. Introduction to Cluster Chemistry; Prentice-Hall International: Englewood Cliffs, NJ, 1990. (c) Metal Clusters; Moskovits, M., Ed.; John Wiley & Sons: New York, 1986. (d) Transition Metal Clusters; Johnson, B. F. G., Ed.; John Wiley & Sons: New York, 1980.
4. See, for example: (a) The Chemistry of Metal Cluster Complexes; Shriver, D. F., Kaesz, H. D., Adams, R. D., Eds.; VCH Publishers: New York, 1990. (b) Mingos, D. M. P.; Wales, D. J. Introduction to Cluster Chemistry; Prentice-Hall International: Englewood Cliffs, NJ, 1990. (c) Metal Clusters; Moskovits, M., Ed.; John Wiley & Sons: New York, 1986. (d) Transition Metal Clusters; Johnson, B. F. G., Ed.; John Wiley & Sons: New York, 1980.
5. Bruce, M. I. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Bruce, M. I., Eds.; Pergamon: Oxford, 1995; Vol. 13.
6. For a review on cluster-stabilized cations, see: McGlinchey, M. J.; Girard, L.; Ruffolo, R. Coord. Chem. Rev. 1995, 143, 331.
7. Cationic, non-hydridic, 50-electron triruthenium clusters are described in the following: (a) Cabeza, J. A.; Lahoz, F. J.; Martín, A. Organometallics 1992, 11, 2754. (b) Field, J. S.; Haines, R. J.; Jay, J. A. J. Organomet. Chem. 1990, 395, C16. (c) Nagra, H. K.; Batchelor, R. J.; Bennet, A. J.; Einstein, F. W. B.; Lathioor, E. C.; Pomeroy, R. K.; Wang, W. J. Am. Chem. Soc. 1996, 118, 1207.
8. Cationic, non-hydridic, 50-electron triruthenium clusters are described in the following: (a) Cabeza, J. A.; Lahoz, F. J.; Martín, A. Organometallics 1992, 11, 2754. (b) Field, J. S.; Haines, R. J.; Jay, J. A. J. Organomet. Chem. 1990, 395, C16. (c) Nagra, H. K.; Batchelor, R. J.; Bennet, A. J.; Einstein, F. W. B.; Lathioor, E. C.; Pomeroy, R. K.; Wang, W. J. Am. Chem. Soc. 1996, 118, 1207.
9. Cationic, non-hydridic, 50-electron triruthenium clusters are described in the following: (a) Cabeza, J. A.; Lahoz, F. J.; Martín, A. Organometallics 1992, 11, 2754. (b) Field, J. S.; Haines, R. J.; Jay, J. A. J. Organomet. Chem. 1990, 395, C16. (c) Nagra, H. K.; Batchelor, R. J.; Bennet, A. J.; Einstein, F. W. B.; Lathioor, E. C.; Pomeroy, R. K.; Wang, W. J. Am. Chem. Soc. 1996, 118, 1207.
10. Cationic, non-hydridic, 47- and 46-electron triruthenium clusters are described in the following: Connelly, N. G.; Forrow, N. J.; Knox, S. A. R.; Macpherson, K. A.; Orpen, G. J. Chem. Soc., Chem. Commun. 1985, 16.
11. Cationic, non-hydridic, 47-electron tricobalt clusters are described in the following: (a) Bedard, R. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 5933. (b) Ziebarth, M. S.; Dahl, L. F. J. Am. Chem. Soc. 1990, 112, 2411.
12. Cationic, non-hydridic, 47-electron tricobalt clusters are described in the following: (a) Bedard, R. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 5933. (b) Ziebarth, M. S.; Dahl, L. F. J. Am. Chem. Soc. 1990, 112, 2411.
13. Cationic, non-hydridic, 48-electron tricobalt clusters are described in the following: (a) Hallgreen, J. E.; Eschbach, C. S.; Seyferth, D. J. Am. Chem. Soc. 1975, 94, 2547. (b) Seyferth, D.; Williams, G. H.; Nivert, C. L. Inorg. Chem. 1977, 16, 758. (c) D'Agostino, M. F.; Mlekuz, M.; Kolis, J. W.; Sayer, B. G.; Rodger, C. A.; Halet, J. F.; Saillard, J. Y.; McGlinchey, M. J. Organometallics 1986, 5, 2345. (d) Edidin, R. T.; Norton, J. R.; Mislow, K. Organometallics 1982, 1, 561. (e) D'Agostino, M. F.; Frampton, C. S.; McGlinchey, M. J. J. Organomet. Chem. 1990, 394, 145. (f) D'Agostino, M. F.; Mlekuz, M.; McGlinchey, M. J. J. Organomet. Chem. 1988, 345, 371. (g) Oison, W. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 7657. (h) Wadepohl, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 247.
14. Cationic, non-hydridic, 48-electron tricobalt clusters are described in the following: (a) Hallgreen, J. E.; Eschbach, C. S.; Seyferth, D. J. Am. Chem. Soc. 1975, 94, 2547. (b) Seyferth, D.; Williams, G. H.; Nivert, C. L. Inorg. Chem. 1977, 16, 758. (c) D'Agostino, M. F.; Mlekuz, M.; Kolis, J. W.; Sayer, B. G.; Rodger, C. A.; Halet, J. F.; Saillard, J. Y.; McGlinchey, M. J. Organometallics 1986, 5, 2345. (d) Edidin, R. T.; Norton, J. R.; Mislow, K. Organometallics 1982, 1, 561. (e) D'Agostino, M. F.; Frampton, C. S.; McGlinchey, M. J. J. Organomet. Chem. 1990, 394, 145. (f) D'Agostino, M. F.; Mlekuz, M.; McGlinchey, M. J. J. Organomet. Chem. 1988, 345, 371. (g) Oison, W. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 7657. (h) Wadepohl, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 247.
15. Cationic, non-hydridic, 48-electron tricobalt clusters are described in the following: (a) Hallgreen, J. E.; Eschbach, C. S.; Seyferth, D. J. Am. Chem. Soc. 1975, 94, 2547. (b) Seyferth, D.; Williams, G. H.; Nivert, C. L. Inorg. Chem. 1977, 16, 758. (c) D'Agostino, M. F.; Mlekuz, M.; Kolis, J. W.; Sayer, B. G.; Rodger, C. A.; Halet, J. F.; Saillard, J. Y.; McGlinchey, M. J. Organometallics 1986, 5, 2345. (d) Edidin, R. T.; Norton, J. R.; Mislow, K. Organometallics 1982, 1, 561. (e) D'Agostino, M. F.; Frampton, C. S.; McGlinchey, M. J. J. Organomet. Chem. 1990, 394, 145. (f) D'Agostino, M. F.; Mlekuz, M.; McGlinchey, M. J. J. Organomet. Chem. 1988, 345, 371. (g) Oison, W. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 7657. (h) Wadepohl, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 247.
16. Cationic, non-hydridic, 48-electron tricobalt clusters are described in the following: (a) Hallgreen, J. E.; Eschbach, C. S.; Seyferth, D. J. Am. Chem. Soc. 1975, 94, 2547. (b) Seyferth, D.; Williams, G. H.; Nivert, C. L. Inorg. Chem. 1977, 16, 758. (c) D'Agostino, M. F.; Mlekuz, M.; Kolis, J. W.; Sayer, B. G.; Rodger, C. A.; Halet, J. F.; Saillard, J. Y.; McGlinchey, M. J. Organometallics 1986, 5, 2345. (d) Edidin, R. T.; Norton, J. R.; Mislow, K. Organometallics 1982, 1, 561. (e) D'Agostino, M. F.; Frampton, C. S.; McGlinchey, M. J. J. Organomet. Chem. 1990, 394, 145. (f) D'Agostino, M. F.; Mlekuz, M.; McGlinchey, M. J. J. Organomet. Chem. 1988, 345, 371. (g) Oison, W. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 7657. (h) Wadepohl, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 247.
17. Cationic, non-hydridic, 48-electron tricobalt clusters are described in the following: (a) Hallgreen, J. E.; Eschbach, C. S.; Seyferth, D. J. Am. Chem. Soc. 1975, 94, 2547. (b) Seyferth, D.; Williams, G. H.; Nivert, C. L. Inorg. Chem. 1977, 16, 758. (c) D'Agostino, M. F.; Mlekuz, M.; Kolis, J. W.; Sayer, B. G.; Rodger, C. A.; Halet, J. F.; Saillard, J. Y.; McGlinchey, M. J. Organometallics 1986, 5, 2345. (d) Edidin, R. T.; Norton, J. R.; Mislow, K. Organometallics 1982, 1, 561. (e) D'Agostino, M. F.; Frampton, C. S.; McGlinchey, M. J. J. Organomet. Chem. 1990, 394, 145. (f) D'Agostino, M. F.; Mlekuz, M.; McGlinchey, M. J. J. Organomet. Chem. 1988, 345, 371. (g) Oison, W. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 7657. (h) Wadepohl, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 247.
18. Cationic, non-hydridic, 48-electron tricobalt clusters are described in the following: (a) Hallgreen, J. E.; Eschbach, C. S.; Seyferth, D. J. Am. Chem. Soc. 1975, 94, 2547. (b) Seyferth, D.; Williams, G. H.; Nivert, C. L. Inorg. Chem. 1977, 16, 758. (c) D'Agostino, M. F.; Mlekuz, M.; Kolis, J. W.; Sayer, B. G.; Rodger, C. A.; Halet, J. F.; Saillard, J. Y.; McGlinchey, M. J. Organometallics 1986, 5, 2345. (d) Edidin, R. T.; Norton, J. R.; Mislow, K. Organometallics 1982, 1, 561. (e) D'Agostino, M. F.; Frampton, C. S.; McGlinchey, M. J. J. Organomet. Chem. 1990, 394, 145. (f) D'Agostino, M. F.; Mlekuz, M.; McGlinchey, M. J. J. Organomet. Chem. 1988, 345, 371. (g) Oison, W. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 7657. (h) Wadepohl, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 247.
19. Cationic, non-hydridic, 48-electron tricobalt clusters are described in the following: (a) Hallgreen, J. E.; Eschbach, C. S.; Seyferth, D. J. Am. Chem. Soc. 1975, 94, 2547. (b) Seyferth, D.; Williams, G. H.; Nivert, C. L. Inorg. Chem. 1977, 16, 758. (c) D'Agostino, M. F.; Mlekuz, M.; Kolis, J. W.; Sayer, B. G.; Rodger, C. A.; Halet, J. F.; Saillard, J. Y.; McGlinchey, M. J. Organometallics 1986, 5, 2345. (d) Edidin, R. T.; Norton, J. R.; Mislow, K. Organometallics 1982, 1, 561. (e) D'Agostino, M. F.; Frampton, C. S.; McGlinchey, M. J. J. Organomet. Chem. 1990, 394, 145. (f) D'Agostino, M. F.; Mlekuz, M.; McGlinchey, M. J. J. Organomet. Chem. 1988, 345, 371. (g) Oison, W. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 7657. (h) Wadepohl, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 247.
20. Cationic, non-hydridic, 48-electron tricobalt clusters are described in the following: (a) Hallgreen, J. E.; Eschbach, C. S.; Seyferth, D. J. Am. Chem. Soc. 1975, 94, 2547. (b) Seyferth, D.; Williams, G. H.; Nivert, C. L. Inorg. Chem. 1977, 16, 758. (c) D'Agostino, M. F.; Mlekuz, M.; Kolis, J. W.; Sayer, B. G.; Rodger, C. A.; Halet, J. F.; Saillard, J. Y.; McGlinchey, M. J. Organometallics 1986, 5, 2345. (d) Edidin, R. T.; Norton, J. R.; Mislow, K. Organometallics 1982, 1, 561. (e) D'Agostino, M. F.; Frampton, C. S.; McGlinchey, M. J. J. Organomet. Chem. 1990, 394, 145. (f) D'Agostino, M. F.; Mlekuz, M.; McGlinchey, M. J. J. Organomet. Chem. 1988, 345, 371. (g) Oison, W. L.; Dahl, L. F. J. Am. Chem. Soc. 1986, 108, 7657. (h) Wadepohl, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 247.
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