Evaluation of the carbene hydride mechanism in the carbon-carbon bond formation process of alkane metathesis through a DFT study

Journal of the American Chemical Society

Volumn 130, Issue 25, 2008, Pages 7984-7987

  Schinzel, Sandra ^a   Chermette, Henry ^a   Copéret, Christophe ^b   Basset, Jean Marie ^b  

^a UNIVERSITÉ LYON 1   (France)

^b UNIVERSITÉ DE LYON   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; HYDROCARBONS; OLEFINS; PARAFFINS; SILICA; SILICATE MINERALS; SILICON COMPOUNDS;

AMERICAN CHEMICAL SOCIETY (ACS); CARBENE; CARBON CARBON BOND FORMATIONS; CYCLOREVERSION (CR); DFT STUDY; ELEMENTARY STEPS; HIGH ENERGIES; INTERCONVERSION; LOW ENERGIES; MAKING PROCESS; OLEFIN METATHESIS; REACTION INTERMEDIATES;

CARBON;

ALKANE; CARBENE; CARBENE HYDRIDE; CYCLOBUTANE; SILICON DIOXIDE; TANTALUM; TANTALUMHYDRIDOCARBENE COMPLEX;

ARTICLE; CHEMICAL BOND; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; GEOMETRY; REACTION ANALYSIS;

EID: 45749133530     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja800474h     Document Type: Article

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