Paramagnetic chloro-, alkoxo-, or azidovanadium(IV) complexes supported by an [ONNO]-type amine bis(phenolate) ligand

European Journal of Inorganic Chemistry

Volumn , Issue 14, 2004, Pages 2861-2867

  Wolff, Fabien ^a   Lorber, Christian ^a   Choukroun, Robert ^a   Donnadieu, Bruno ^a  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

Amines; Paramagnetism; Vanadium

Indexed keywords

CRYSTAL ATOMIC STRUCTURE; ELECTRON SPIN RESONANCE SPECTROSCOPY; LIGANDS; VANADIUM COMPOUNDS;

AMINE LIGAND; AMINO NITROGEN; COMPLEX 1; CRYSTALS STRUCTURES; DONOR ATOMS; EXPERIMENTAL CONDITIONS; NITROGEN DONORS; PHENOLATE GROUPS; PHENOLATE LIGANDS; TRANS CONFIGURATION;

PARAMAGNETISM;

AMINE; CHLORINE DERIVATIVE; LIGAND; NITROGEN; TOLUENE; VANADIUM DERIVATIVE;

ARTICLE; CHELATION; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; MAGNETISM; REACTION ANALYSIS;

EID: 4544251241     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300922     Document Type: Article

References (65)

1. For recent reviews see: [1a] V. C. Gibson, S. K. Spitzmesser, Chem. Rev. 2003, 103, 283-315.
2. [1b] G. J. P. Britovsek, V. C. Gibson, D. F. Wass, Angew. Chem. Int. Ed. 1999, 38, 429-447.
3. [2a] J. D. Scollard, D. H. McConville, J. Am. Chem. Soc. 1996, 118, 10008-10009.
4. [2b] J. D. Scollard, D. H. McConville, N. C. Payne, J. J. Vittal, Macromolecules 1996, 29, 5241-5243.
5. [3a] R. Baumann, W. M. Davis, R. R. Schrock, J. Am. Chem. Soc. 1997, 119, 3830-3831.
6. [3b] R. R. Schrock, F. Schattenmann, M. Aizenberg, W. M. Davis, Chem. Commun. 1998, 1999-2000.
7. [3c] R. Baumann, R. R. Schrock, J. Organomet Chem. 1998, 557, 69-75.
8. [3d] R. R. Schrock, R. Baumann, S. M. Reid, J. T. Goodman, R. Stumpf, D. M. Davis, Organometallics 1999, 18, 3649-3670.
9. [3e] J. T. Goodman, R. R. Schrock, Organometallics 2001, 20, 5205-5211.
10. [4a] A. Shafir, M P. Power, G. D. Whitener, J. Arnold, Organometallics 2001, 20, 1365-1369.
11. [4b] R. M. Gauvin, C. Lorber, R. Choukroun, B. Donnadieu, J. Kress, Eur. J. Inorg. Chem. 2001, 2337-2346.
12. [4c] Y. M. Jeon, S. J. Park, J. Heo, K. Kim, Organometallics 1998, 77, 3161-3163.
13. [4d] S. Tinkler, R. J. Deeth, D. J. Duncalf, A. McCamley, Chem. Commun. 1996, 2633-2634.
14. [4e] F. G. N. Clocke, T. J. Geldbach, P. B. Hitchcock, J. B. Love, J. Organomet. Chem. 1996, 506, 343-345.
15. [4f] N. A. H. Male, M. Thornton-Pett, M. Bochmann, J. Chem. Soc., Dalton Trans. 1997, 2487-2494.
16. [4g] V. C. Gibson, B. S. Kimberley, A. J. P. White, D. J. Williams, P. Howard, Chem. Commun. 1998, 313-314.
17. [4h] C. H. Lee, Y.-H. La, S. J. Park, J. W. Park, Organometallics 1998, 17, 3648-3655.
18. [5a] E. Y. Tshuva, I. Goldberg, M. Kol, J. Am. Chem. Soc. 2000, 122, 10706-10707.
19. [5b] E. Y. Tshuva, I. Goldberg, M. Kol, H. Weitman, Z. Goldschmidt, Chem. Commun. 2000, 379-380.
20. [5c] E. Y. Tshuva, I. Goldberg, M. Kol, Z. Goldschmidt, Chem. Commun. 2001, 2120-2121.
21. [5d] E. Y. Tshuva, S. Groysman, I. Goldberg, M. Kol, Z. Goldschmidt, Organometallics 2002, 21, 662-670.
22. [5e] E. Y. Tshuva, I. Goldberg, M. Kol, Z. Goldschmidt, Organometallics 2001, 20, 3017-3028.
23. [5f] E. Y. Tshuva, I. Goldberg, M. Kol, Z. Goldschmidt, Inorg. Chem. 2001, 40, 4263-4270.
24. [6a] Y. Nakayama, K. Watanabe, N. Ueyama, A. Nakamura, A. Harada, J. Okuda, Organometallics 2000, 19, 2498-2503.
25. [6b] R. M. Gauvin, J. A. Osborn, J. Kress, Organometallics 2000, 19, 2944-2946.
26. [6c] H. Mack, M. S. Eisen, J. Chem. Soc., Dalton Trans. 1998, 917-921.
27. [6d] M. G. Thorn, Z. C. Etheridge, P. E. Fanwick, I. P. Rothwell, Organometallics 1998, 17, 3636-3638.
28. [6e] X. Bei, D. C. Swenson, R. F. Jordan, Organometallics 1997, 16, 3282-3302.
29. See for example: [7a] M. Mitani, R. Furuyama, J-I. Mohri, J. Saito, S. Ishii, H. Terao, H. Tanaka, T. Fujita, J. Am. Chem. Soc. 2003, 125, 4293-4305.
30. [7b] S. Matsui, Y. Tohi, M. Mitani, J. Saito, H. Makio, H. Tanaka, M. Nitabaru, T. Nakano, T. Fujita, Chem. Lett. 1999, 1065-1066.
31. [7c] S. Matsui, T. Fujita, Catal. Today 2001, 66, 63-73.
32. [7d] J. Saito, M. Mitani, S. Matsui, J-I. Mohri, S. Kojoh, N. Kashiwa, T. Fujita, Angew. Chem. Int. Ed. 2001, 40, 2918-2920.
33. [7e] Y. Susuki, N. Kashiwa, T. Fujita, Chem. Lett. 2002, 358-359.
34. [7f] M. Mitami, T. Nakano, T. Fujita, Chem. Eur. J. 2003, 9, 2396-2402.
35. [8a] J. Tian, G. W. Coates, Angew. Chem. Int. Ed. 2000, 39, 3626-3629.
36. [8b] M. Fujita, G. W. Coates, Macromolecules 2002, 35, 9640-9647.
37. [8c] J. Tian, P. D. Hustad, G. W. Coates, J. Am. Chem. Soc. 2002, 124, 3614-3621.
38. [9a] C. Lorber, R. Choukroun, B. Donnadieu, Inorg. Chem. 2003, 42, 673-675.
39. [9b] C. Lorber, R. Choukroun, B. Donnadieu, Inorg. Chem. 2002, 41, 4217-4226.
40. [9c] R. Choukroun, B. Donnadieu, C. Lorber, P.-M. Pellny, W. Baumann, U. Rosenthal, Chem. Eur. J. 2000, 6, 4505-4509.
41. [9d] R. Choukroun, B. Donnadieu, C. Lorber, Chem. Eur. J. 2002, 8, 2700-2704.
42. [9e] R. Choukroun, C. Lorber, B. Donnadieu, Organometallics 2002, 21, 1124-1126.
43. [9f] F. Wolff, R. Choukroun, C. Lorber, B. Donnadieu, Eur. J. Inorg. Chem. 2003, 628-632.
44. C. Lorber, B. Donnadieu, R. Choukroun, Organometallics 2000, 19, 1963-1966.
45. C. Lorber, B. Donnadieu, R. Choukroun, J. Chem. Soc., Dalton Trans. 2000, 4497-4498.
46. F. Wolff, C. Lorber, R. Choukroun, B. Donnadieu, Inorg. Chem. 2003, 42, 7839-7845.
47. I. M. Thomas, Can J. Chem. 1961, 39, 1386-1388.
48. 3 and related azides, see: [14a] L. Bretherick, Handbook of Reactive Chemical Hazards; Butterworth: London, 1975; pp. 775-776.
49. [14b] Committee on Prudent Practices for Handling, Storage, and Disposal of Chemicals in Laboratories Prudent Practices in the Laboratory, Handling and Disposal of Chemicals; National Academic Press: Washington, D. C. 1995; pp. 165 and 102.
50. A. Altomare, G. Cascarano, G. Giacovazzo, A. Guagliardi, M. C. Burla, G. Polidori, M. Camalli, J. Appl. Crystallogr. 1994, 27, 435.
51. SHELX97 [includes SHELXS-97, SHELXL-97, CIFTAB], Programs for Crystal Structure Analysis (Release 97-2); G. M. Sheldrick, University of Göttingen, Institut für Anorganische Chemie, Tammanstraße 4, 3400 Göttingen, Germany, 1998.
52. L. J. Farrugia, J. Appl. Crystallogr. 1999, 32, 837-838.
53. N. Walker, D. Stuart, Acta Crystallogr., Sect. A 1983, 39, 158-166.
54. R. Choukroun, P. Moumboko, S. Chevalier, M. Etienne, B. Donnadieu, Angew. Chem. Int. Ed. 1998, 37, 3169.
55. C. Lorber, R. Choukroun, unpublished results.
56. D. C. Bradley, M. H. Gitlitz, J. Chem. Soc., A 1969, 980-985.
57. W. J. Evans, L. A. Edinger, J. W. Ziller, Polyhedron 1999, 18, 1475-1477.
58. C. Lorber, J. P. Donahue, C. A. Goddard, E. Nordlander, R. H. Holm, J. Am. Chem. Soc. 1998, 720, 8102-8112.
59. caution: Organic and inorganic azides are potentially explosive compounds and should be handled with great care. Reflux in toluene was realized on a 20 mg scale to prevent any explosion and in a stainless steel reactor for safety.
60. Generally, phenoxide bond lengths are ca 1.90 Å. Very few vanadium compounds are known with phenoxide V-O bond lengths < 1.79 Å, among which: [25a] V. Vergopoulos, S. Jantzen, N. Julien, E. Rose, D. Rehder, Z. Naturfosh. B 1994, 49, 1127-1130.
61. [25b] N. F. Choudhary, N. G. Connelly, P. B. Hitchcock, G. J. Leigh, J. Chem. Soc., Dalton Trans. 1999, 4437-4446.
62. [25c] A. Hills, D. L. Hughes, G. J. Leigh, J. R. Sanders, J. Chem. Soc., Dalton Trans. 1991, 61-64.
63. [25d] P. J. Toscano, E. J. Schermerhorn, C. Dettelsbach, D. Macherone, J. Zubieta, J. Chem. Soc., Chem. Commun. 1991, 933-934.
64. [25e] V. J. Murphy, H. Turner, Organometallics 1997,16, 2495-2497.
65. II related systems C. Lorber, R. Choukroun, Organometallics, submitted).