Vanadium(V) Complexes of a Chelating Dianionic [ONNO]-Type Amine Bis(Phenolate) Ligand: Synthesis and Solid State and Solution Structures

Inorganic Chemistry

Volumn 42, Issue 24, 2003, Pages 7839-7845

  Wolff, Fabien ^a   Lorber, Christian ^a   Choukroun, Robert ^a   Donnadieu, Bruno ^a  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AMINE; ANION; CHELATING AGENT; CHLORIDE; DIMETHYLAMINE; HYDROGEN; LIGAND; METHYL GROUP; NITROGEN; PHENOL DERIVATIVE; SILICON DERIVATIVE; TOLUENE; VANADIUM DERIVATIVE;

ARTICLE; CHLORINATION; CIS TRANS ISOMERISM; ENVIRONMENTAL TEMPERATURE; MATHEMATICAL COMPUTING; NUCLEAR MAGNETIC RESONANCE; NUCLEAR OVERHAUSER EFFECT; SOLID STATE; SPECTROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY ANALYSIS;

EID: 0344586252     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034742f     Document Type: Article

References (57)

1. For recent reviews see: (a) Gibson, V. C.; Spitzmesser, S. K. Chem. Rev. 2003, 103, 283-315.
2. (b) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed., 1999, 38, 429-447.
3. (a) Scollard, J. D.; McConville, D. H. J. Am. Chem. Soc. 1996, 118, 10008-10009.
4. (b) Scollard, J. D.; McConville, D. H., Payne, N. C.; Vittal, J. J. Macromolecules 1996, 29, 5241-5243.
5. (a) Baumann, R.; Davis, W. M.; Schrock, R. R. J. Am. Chem. Soc. 1997, 119, 3830-3831.
6. (b) Schrock, R. R.; Schattenmann, F.; Aizenberg, M.; Davis, W. M. Chem. Commun. 1998, 1999-2000.
7. (c) Baumann, R.; Schrock, R. R. J. Organomet. Chem. 1998, 557, 69-75.
8. (d) Schrock, R. R.; Baumann, R.; Reid, S. M.; Goodman, J. T.; Stumpf, R. ; Davis, D. M. Organometallics 1999, 18, 3649-3670.
9. (e) Goodman, J. T.; Schrock, R. R. Organometallics 2001, 20, 5205-5211.
10. (a) Shafir, A.; Power, M. P.; Whitener, G. D.; Arnold, J. Organometallics 2001, 20, 1365-1369.
11. (b) Gauvin, R. M.; Lorber, C.; Choukroun, R.; Donnadieu, B.; Kress, J. Eur. J. Inorg. Chem. 2001, 2337-2346.
12. (c) Jeon, Y. M.; Park, S. J.; Heo, J.; Kim, K. Organometallics 1998, 17, 3161-3163.
13. (d) Tinkler, S.; Deeth, R. J.; Duncalf, D. J.; McCamley, A. J. Chem. Soc., Chem. Commun, 1996, 2633-2634.
14. (e) Clocke, F. G. N.; Geldbach, T. J.; Hitchcock, P. B.; Love, J. B. J. Organomet. Chem. 1996, 506, 343-345.
15. (g) Male, N. A. H.; Thornton-Pett, M.; Bochmann, M. J. Chem. Soc., Dalton Trans. 1997, 2487-2494.
16. (h) Gibson, V. C.; Kimberley, B. S.; White, A. J. P.; Williams, D. J.; Howard, P. J. Chem. Soc., Chem. Commun. 1998, 313-314.
17. (i) Lee, C. H.; La, Y.-H.; Park, S. J.; Park, J. W. Organometallics 1998, 17, 3648-3655.
18. (a) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706-10707.
19. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Weitman, H.; Goldschmidt, Z. Chem. Commun. 2000, 379-380.
20. (c) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Chem. Commun. 2001, 2120-2121.
21. (d) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2002, 21, 662-670.
22. (e) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Organometallics 2001, 20, 3017-3028.
23. (f) Tshuva, E. Y.; Goldberg, I.; Kol, M.; Goldschmidt, Z. Inorg. Chem. 2001, 40, 4263-4270.
24. (a) Nakayama, Y.; Watanabe, K.; Ueyama, N.; Nakamura, A.; Harada, A.; Okuda, J. Organometallics 2000, 19, 2498-2503.
25. (b) Gauvin, R. M.; Osborn, J. A.; Kress, J. Organometallics 2000, 19, 2944-2946.
26. (c) Mack, H.; Eisen, M. S. J. Chem. Soc., Dalton Trans. 1998, 917-921.
27. (d) Thorn, M. G.; Etheridge, Z. C.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1998, 17, 3636-3638.
28. (e) Bei, X.; Swenson, D. C.; Jordan, R. F. Organometallics 1997, 16, 3282-3302.
29. (a) Ziegler, K.; Holzkamp, E.; Breil, H.; Martin, H. Angew. Chem. 1955, 67, 426.
30. (b) Natta, G.; Pino, P.; Corradini, P.; Danusso, F.; Mantica, E.; Mazzanti, G.; Moraglio, G. J. Am. Chem. Soc. 1955, 77, 1708-1710.
31. For recent reviews see: (a) Coates, G. W.; Hustad, P. D.; Reinartz, S. Angew. Chem., Int. Ed. 2002, 41, 2236-2257.
32. (b) Hagen, H.; Boersma, J.; van Koten, G. Chem. Soc. Rev. 2002, 31, 357-364.
33. (c) Gambarotta, S. Coord. Chem. Rev. 2003, 237, 229-243.
34. (a) Lorber, C.; Choukroun, R.; Donnadieu, B. Inorg. Chem. 2003, 42, 673-675.
35. (b) Lorber, C.; Choukroun, R.; Donnadieu, B. Inorg. Chem. 2002, 41, 4217-4226.
36. (c) Choukroun, R.; Donnadieu, B.; Lorber, C.; Pellny, P.-M.; Baumann, W. ; Rosenthal, U. Chem. Eur. J. 2000, 6, 4505-4509.
37. (d) Choukroun, R.; Donnadieu, B.; Lorber, C. Chem. Eur. J. 2002, 8, 2700-2704.
38. (e) Choukroun, R.; Lorber, C.; Donnadieu, B. Organometallics 2002, 21, 1124-1126.
39. (f) Wolff, F.; Choukroun, R.; Lorber, C.; Donnadieu, B. Eur. J. Inorg. Chem. 2003, 628-632.
40. Lorber, C.; Donnadieu, B.; Choukroun, R. Organometallics 2000, 19, 1963-1966.
41. Lorber, C.; Donnadieu, B.; Choukroun, R. J. Chem. Soc., Dalton Trans. 2000, 4497-4498.
42. Choukroun, R.; Gervais, D. Inorg. Chim. Acta 1978, 27, 163-166.
43. Mittal, R. K.; Mehrotra, R. C. Z. Anorg. Allg. Chem. 1964, 327, 311-314.
44. Choukroun, R.; Dia, A.; Gervais, D. Inorg. Chim. Acta 1979, 34, 187-189.
45. Choukroun, R.; Gervais, D. J. Chem. Soc, Dalton Trans. 1980, 9, 1800-1802.
46. Altomare, A.; Cascarano, G.; Giacovazzo, G.; Guagliardi, A.; Burla, M. C.; Polidori, G.; Camalli, M. J. Appl. Crystallogr. 1994, 27, 435.
47. Sheldrick, G. M. SHELX97, Programs for Crystal Structure Analysis (Release 97-2); Institüt für Anorganische Chemie: Tammanstrasse 4, D-3400 Göttingen, Germany, 1998 (includes SHELXS97, SHELXL97, CIFTAB).
48. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837-838.
49. Walker, N.; Stuart, D. Acta Crystallogr. A 1983, 39, 158-166.
50. Flack, H. D Acta Crystallogr, A 1983, 39, 876-881.
51. 3.
52. 1H NMR studies of a few crystals of 1a still present features of both cis and trans isomers. As we have shown that the interconversion between the isomers is not possible, it suggests that we may have obtained mixture of crystals of the two isomers.
53. Nugent, W. A.; Mayer, J. M. In Metal-Ligand Multiple Bonds; Wiley-Interscience: New York, 1988.
54. 2 sidearm that are less intense in isomer A than in isomer B.
55. 2-N methylenic protons.
56. Hanich, J.; Krestel, M.; Muller, U.; Denicke, K.; Rehder, D. Z. Naturforsch. B 1984, 39, 1686-1690.
57. It is unclear why starting from a mixture of two isomers of 1a-c we end up with a single isomer of 2; one possible reason would be the intrinsic instability of the unobserved isomer.