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Volumn , Issue 10, 1999, Pages 1065-1066

New bis(salicylaldiminato) titanium complexes for ethylene polymerization

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Indexed keywords


EID: 0033235152     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1999.1065     Document Type: Article
Times cited : (219)

References (26)
  • 19
    • 0009191913 scopus 로고    scopus 로고
    • note
    • 3); δ 1.47 (s, 9H), 6.8-7.5 (m, 8H), 8.67 (s, 1H), 13.95 (s, 1H).
  • 20
    • 0009192999 scopus 로고    scopus 로고
    • note
    • 3 solution.)
  • 21
    • 0000219699 scopus 로고    scopus 로고
    • DFT calculation has been widely used for structural determination of transition metal complexes, c.f; L. Deng, T. Zieglar, T. K. Woo, P. Margl, and L. Fan, Organometallics, 17, 3240 (1998). All calculations were performed using gradient corrected density functional method BLYP, by means of the Amsterdam Density Functional (ADF) program. We used the triple -ζ basis set on the metal center, the double-ζ basis sel on the Cl, N and O atoms, and the single-ζ basis set on the other atoms.
    • (1998) Organometallics , vol.17 , pp. 3240
    • Deng, L.1    Zieglar, T.2    Woo, T.K.3    Margl, P.4    Fan, L.5
  • 22
    • 0009193309 scopus 로고    scopus 로고
    • note
    • -1.
  • 23
    • 0009189163 scopus 로고    scopus 로고
    • note
    • General polymerization procedure; Flow of ethylene gas (100 L/h) was charged into 250 ml of toluene at 25 °C. To this solution, MAO (Albemarle MAO. 1.2mmol/ml of a toluene solution) and a toluene solution of a complex was added at designated polymerization temperature. After the prescribed time, 25 ml of isobutanol was added to terminate the polymerization.
  • 24
    • 0002800999 scopus 로고
    • 0.7 ; R. Chiang, J. Polymer Sci., 36, 91 (1959). Intrinsic viscosity [η] was measured in decalin at 135 °C using an Ubbelohde viscometer. The molecular weight distribution (Mw/Mn) value was ca. 2, determined by GPC measurement.
    • (1959) J. Polymer Sci. , vol.36 , pp. 91
    • Chiang, R.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.