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Volumn , Issue 22, 2008, Pages 2547-2549

First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGENASE; IRON COMPLEX;

EID: 44349146712     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b801373j     Document Type: Article
Times cited : (49)

References (42)
  • 33
    • 44349163891 scopus 로고    scopus 로고
    • VT NMR experiments did not reveal any dynamic exchange between the two forms observed in solution. They possibly could differ in the orientation of the R group attached to the nitrogen atom. A room temperature IR spectrum of the sample prepared for NMR studies revealed a ν(CO) pattern similar to that depicted above for the mixture of protonated isomers. This observation indicates that ν(CO) bands and NMR signals belong to the same N-protonated species
    • VT NMR experiments did not reveal any dynamic exchange between the two forms observed in solution. They possibly could differ in the orientation of the R group attached to the nitrogen atom. A room temperature IR spectrum of the sample prepared for NMR studies revealed a ν(CO) pattern similar to that depicted above for the mixture of protonated isomers. This observation indicates that ν(CO) bands and NMR signals belong to the same N-protonated species
  • 38
    • 44349159402 scopus 로고    scopus 로고
    • 1/2 where n is the number of electrons involved in the catalytic process (n = 2), F is the Faraday constant, A is the electrode area, D is the diffusion coefficient of the catalyst, k is the rate constant of the catalytic process, and y is the order of the reaction with respect to the substrate (HA), see
    • J.-F. Capon S. Ezzaher F. Gloaguen F. Y. Pétillon P. Schollhammer J. Talarmin Chem.-Eur. J. 2008 14 1954
    • (2008) Chem.-Eur. J. , vol.14 , pp. 1954
    • Capon, J.-F.1    Ezzaher, S.2    Gloaguen, F.3    Pétillon, F.Y.4    Schollhammer, P.5    Talarmin, J.6


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.