Synthesis, crystal structure and protonation of the asymmetric iron-only hydrogenase model [Fe2(CO)3(μ-pdt){μ,η2-Ph2PCH2CH2P(Ph)CH2CH2PPh2}] (pdt = SCH2CH2CH2S)

Inorganic Chemistry Communications

Volumn 10, Issue 1, 2007, Pages 66-70

  Hogarth, Graeme ^a   Richards, Idris ^a  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

Diiron; Dithiolate; Fluxionality; Hydride; Iron only hydrogenase; Triphos

Indexed keywords

EID: 33845187051     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2006.09.005     Document Type: Article

References (26)

1. Nicolet Y., Piras C., Legrand P., Hatchikian C.E., and Fontecilla-Camps J.C. Structure 7 (1999) 13
2. Peters J.W., Lanzilotta W.N., Lemon B., and Seefeldt L.C. Science 282 (1998) 1853
3. Lemon B.J., and Peters J.W. Biochemistry 38 (1999) 12969
4. Nicolet Y., De Lacy A.L., Vernéde X., Fernandez V.M., Hatchikian E.C., and Fontecilla-Camps J.C. J. Am. Chem. Soc. 123 (2001) 1596
5. Fan H.-J., and Hall M.B. J. Am. Chem. Soc. 123 (2001) 3828
6. Georgakaki I.P., Thomson L.M., Lyon E.J., Hall M.B., and Darensbourg M.Y. Coord. Chem. Rev. 238-239 (2003) 255
7. Evans D.J., and Pickett C.J. Chem. Soc. Rev. 32 (2003) 268
8. Rauchfuss T.B. Inorg. Chem. 43 (2004) 14
9. Sun L., Åkermark B., and Ott S. Coord. Chem. Rev. 249 (2005) 1653
10. Liu X., Ibrahim S.K., Tard C., and Pickett C.J. Coord. Chem. Rev. 249 (2005) 1641
11. Tye J.W., Darensbourg M.Y., and Hall M.B. J. Am. Chem. Soc. 45 (2006) 552
12. Lyon E.J., Georgakaki I.P., Reibenspies J.H., and Darensbourg M.Y. Angew. Chem., Int. Ed. Engl. 38 (1999) 3178
13. Lyon E.J., Georgakaki I.P., Reibenspies J.H., and Darensbourg M.Y. J. Am. Chem. Soc. 123 (2001) 3268
14. Zhao X., Georgakaki I.P., Miller M.L., Yarbrough J.C., and Darensbourg M.Y. J. Am. Chem. Soc. 123 (2001) 9710
15. Zhao X., Georgakaki I.P., Miller M.L., Mejia-Rodriguez R., Chiang C.-Y., and Darensbourg M.Y. Inorg. Chem. 41 (2002) 3917
16. Chong D., Georgakaki I.P., Mejia-Rodriguez R., Sanabria-Chinchilla J., Soriaga M.P., and Darensbourg M.Y. Dalton Trans. (2003) 4158
17. Mejia-Rodriguez R., Chong D., Reibenspies J.H., Soriaga M.P., and Darensbourg M.Y. J. Am. Chem. Soc. 126 (2004) 12004
18. Gloaguen F., Lawrence J.D., and Rauchfuss T.B. J. Am. Chem. Soc. 123 (2001) 9476
19. Gloaguen F., Lawrence J.D., Rauchfuss T.B., Bénard M., and Rohmer M.-M. Inorg. Chem. 41 (2002) 6573
20. Nehring J., and Heinekey D.M. Inorg. Chem. 42 (2003) 4288
21. G. Hogarth, I. Richards, J. Organomet. Chem, submitted for publication.
22. G. Hogarth, I. Richards, unpublished results.
23. Seyferth D., Womack G.B., Gallagher M.K., Cowie M., Hames B.W., Fackler J.P., and Mazany A.M. Organometallics 6 (1987) 283
24. 39: C, 57.42, H, 4.67; Found C, 57.54, H, 3.86.
25. 2 = 0.0998 (all data), for 478 parameters.
26. 2, 298 K): δ 88.9 (s), 85.3 (s), 46.4 (s).