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58149191841
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Spectroscopic data for Gb5-OBn: 1H NMR (500 MHz, D 2O, δ 7.47-7.38 (m, 5H, Ph, 4.91 (d, J, 11.7 Hz, 1H. PhCH2, 4.88 (d, J, 3.8 Hz. H-1‴, 4.74 (d, J, 11.8 Hz, 1H, PhCH2, 4.66 (d, J, 8.6 Hz, 1H, H-l, 4.52 (d, J, 8.1 Hz, 1H, H-1, 4.48 (d, J, 7.8 Hz. 1H, H-1, 4.42 (d, J, 7.7 Hz, 1H, H-1, 4.35 (t, J, 6.3 Hz, 1H, 4.22 (d, J, 1.7 Hz, 1H, 4.15 (d, J, 2.7 Hz, 1H, 4.03 (m, 1H, 4.01 (m, 1H, 3.97 (dd, J, 12.5, 1.6 Hz, 1H, 3.94 (dd, J, 10.1. 2.9 Hz, Hi, 3.91-3.85 (m. 4H, 3.82 (d, J, 4.4 Hz, 1H, 3.79 (d, J, 4.4 Hz. 1H, 3.78-3.69 (m, 6H, 3.68-3.65 (m, 3H, 3.64-3.61 (m, 2H, 3.60-3.53 (m, 4H, 3.50 (dd, J, 9.9, 7.9 Hz, 1H, 3.32 (t, J, 8.6 Hz. 1H, 1.99 (s, 3H, CH3CONH, l3C NMR 125 MHz, D2O, δ 175.2, 136.6, 128.8, 128.76, 128.5, 104.8, 103.3, 103.0. 101.0
-
26Na ([M + Na]+) 982.3380, found 982.3405.
-
-
-
-
45
-
-
36248930468
-
-
Bernatchez, S.; Gilbert. M.; Blanchard. M.-C.; Karwaski. M.-F.; Li, J.; DeFrees, S.; Wakarchuk, W. W. Glycohiology 2007,17, 1333-1343.
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Bernatchez, S.1
Gilbert, M.2
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DeFrees, S.6
Wakarchuk, W.W.7
-
46
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-
0141794517
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-
Shao. J; Li, M.; Jia, Q.; Lu, Y.; Wang, P. G. FEES Lett. 2003, 553, 99-103.
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FEES Lett
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, pp. 99-103
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Shao, J.1
Li, M.2
Jia, Q.3
Lu, Y.4
Wang, P.G.5
-
47
-
-
58149184288
-
-
Li, M, Liu, X.-W, Shao. J; Shen, J, Jia, Q, Yi, W, Song, J. K.;
-
Li, M.; Liu, X.-W.; Shao. J; Shen, J.; Jia, Q.; Yi, W.; Song, J. K.;
-
-
-
-
49
-
-
58149177749
-
-
Spectroscopic data for Globo-H-OBn: 1H NMR (500 MHz, D 2O):δ 7.46-7.38 (m, 5H, Ph, 5.20 (d, J, 4.1 Hz, 1H. H-1d‴, 4.91 (d, J =11.7 Hz, 1H, PhCH2, 4.86 (d, J, 3.9 Hz, 1H, H-1‴, 4.74 (d, J, 11.6 Hz, 1H. PhCH 2, 4.59 (d, J, 7.7 Hz, 1H, H-1, 4.53 (d,.J, 7.4 Hz. 1H. H-1, 4.51 (d, J, 6.7 Hz, 1H, H-1, 4.48 (d,.J, 7.7 Hz, 1H, H-1, 4.35 (t, J, 6.4 Hz, 1H, 4.22-4.18 (m, 2H, 4.07 (d, J, 2.1 Hz, 1H, 4.00 (d, J, 3.0 Hz, 1H, 3.98-3.94 (m, 3H, 3.91 (dd, J, 10.6, 2.8 Hz, 1H, 3.88-3.84 (m, 3H, 3.83-3.79 (m, 4H, 3.77 3.72 (m, 7H, 3.70-3.65 (m, 5H, 3.64-3.60 (m, 5H, 3.58-3.53 (m, 3H, 3.33 (t. J, 8.6 Hz. 1H, 2.01 (s, 3H. CH3CONH, 1.19 (d, J, 6.6 Hz, 3H, CH3 of fucose, 13C NMR-DEPT125 MHz, D 2O, δ 128.8, 128.77. 128.5, 104.0. 103.3, 102.1, 101.0, 100.5, 99.3
-
+) 1128.3959, found 1128.3981.
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-
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