CrCl2-promoted stereospecific and stereoselective alkyl- and silylcyclopropanation of α,β-unsaturated amides

Journal of Organic Chemistry

Volumn 73, Issue 10, 2008, Pages 3828-3836

  Concellón, José M ^a   Rodríguez Solla, Humberto ^a   Méjica, Carmen ^a   Blanco, Elena G ^a   García Granda, Santiago ^b   Díaz, M Rosario ^b  

^a UNIVERSITY OF OVIEDO   (Spain)

^b Departamento de Química Física e Analítica

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; CHEMICAL BONDS; CHROMIUM COMPOUNDS; CYCLOADDITION; REACTION KINETICS; STEREOSELECTIVITY;

CARBENE COMPLEXES; CYCLOPROPANATION REACTION.; SILYLCYCLOPROPANATION; STEREOGENIC CENTERS;

AMIDES;

ALDEHYDE; AMIDE; CARBENE; CARBENOID; CHROMIUM CHLORIDE; SILYLCYCLOPROPYL AMIDE; CHLORIDE; CHROMIUM DERIVATIVE; CYCLOPROPANE DERIVATIVE; SILANE DERIVATIVE;

ARTICLE; CYCLOPROPANATION; NUCLEAR OVERHAUSER EFFECT; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; STEREOSPECIFICITY; SYNTHESIS; X RAY CRYSTALLOGRAPHY; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; STEREOISOMERISM;

AMIDES; CHLORIDES; CHROMIUM COMPOUNDS; CYCLIZATION; CYCLOPROPANES; MOLECULAR STRUCTURE; SILANES; STEREOISOMERISM;

EID: 43449095007     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo800103t     Document Type: Article

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46. 3).
47. The geometries of the stationary points were fully optimized, and characterized by frequency calculations.
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