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Volumn , Issue 8, 2004, Pages 1347-1350

Preparation of cyclopropylsilanes from terminal alkenes with organochromium reagents

Author keywords

Chromium(II); Cyclopropane; Cyclopropylsilane

Indexed keywords

ALKENE DERIVATIVE; CHROMIUM DERIVATIVE; CYCLOPROPANE DERIVATIVE; REAGENT; SILANE DERIVATIVE;

EID: 3142658804     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-825612     Document Type: Article
Times cited : (20)

References (23)
  • 17
    • 0010539524 scopus 로고
    • (a) Oxidation of 5 with pyridinium chlorochromate produced the corresponding ketone in 83% yield, which was identical to the ketone in the following literature: Ramig, K.; Bhupathy, M.; Cohen, T. J. Org. Chem. 1989, 54, 4404.
    • (1989) J. Org. Chem. , vol.54 , pp. 4404
    • Ramig, K.1    Bhupathy, M.2    Cohen, T.3
  • 18
    • 3142674538 scopus 로고    scopus 로고
    • note
    • (b) The structure of 5 was also confirmed by X-ray crystallography.
  • 21
    • 3142755179 scopus 로고    scopus 로고
    • note
    • 2, trans:cis = 68:32) along with unreacted allyl benzyl ether in 63% yield (Scheme 2). These results suggest that the reactive species of the silylcyclopropanation is not a carbenoid but the species derived from 6 and TMEDA. (Equation Presented)
  • 23
    • 3142664236 scopus 로고    scopus 로고
    • note
    • 2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.