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Volumn 27, Issue 8, 2008, Pages 1797-1803

Syn-anti isomerization by intramolecular alkene rotation: Study of the dynamics of the bicyclo[2.2.1]hept-2-ene ligands in a diplatinum(I) complex and its lewis acid adducts

Author keywords

[No Author keywords available]

Indexed keywords

BOND LENGTH; ION EXCHANGE; ISOMERIZATION; LIGANDS; METAL COMPLEXES; OLEFINS;

EID: 43249092871     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7010547     Document Type: Article
Times cited : (7)

References (72)
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    • Abel; E. W, Stone; F. G. A, Wilkinson, G, Eds, Pergamon: Oxford, U.K, Chapter 39
    • (a) Hartley, F. R. In Comprehensive Organometallic Chemistry; Abel; E. W., Stone; F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K., 1982; Vol. 6, Chapter 39.
    • (1982) Comprehensive Organometallic Chemistry , vol.6
    • Hartley, F.R.1
  • 7
    • 43249090569 scopus 로고
    • Abel, E. W, Stone, F. G. A, Wilkinson, G, Eds, Pergamon: Oxford, U.K, Chapter 9
    • (b) Young, G. B. In Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 9, Chapter 9.
    • (1995) Comprehensive Organometallic Chemistry , vol.9
    • Young, G.B.1
  • 27
    • 3042743511 scopus 로고    scopus 로고
    • Sprengers, J. W.; Agerbeek; M, J.; Elsevier, C. J.; Kooijman, H.; Spek, A. L. Organometallics 2004, 23, 3117.
    • (h) Sprengers, J. W.; Agerbeek; M, J.; Elsevier, C. J.; Kooijman, H.; Spek, A. L. Organometallics 2004, 23, 3117.
  • 46
    • 43249114105 scopus 로고    scopus 로고
    • 3.
    • 3.
  • 58
    • 43249085973 scopus 로고    scopus 로고
    • 31P signals in the phosphido region indicate the presence of only small amounts of compound 1 being in equilibrium with 2 (ca. 10%).
    • 31P signals in the phosphido region indicate the presence of only small amounts of compound 1 being in equilibrium with 2 (ca. 10%).
  • 67
    • 43249113371 scopus 로고    scopus 로고
    • Structure 3a might theoretically be in a rapid equilibrium with a structure related to 2c by fast intramolecular hydride exchange through the Pt-Pt bond; however there is no analytical proof for this suggestion.
    • Structure 3a might theoretically be in a rapid equilibrium with a structure related to 2c by fast intramolecular hydride exchange through the Pt-Pt bond; however there is no analytical proof for this suggestion.
  • 69
    • 43249097267 scopus 로고    scopus 로고
    • Hägele, G.; Reinemer, P.; Grzonka, M. Workshop.,Computer in der Chemie Softwareentwicklung in der Chemie 1988, 2, 241.
    • (b) Hägele, G.; Reinemer, P.; Grzonka, M. Workshop.,Computer in der Chemie Softwareentwicklung in der Chemie 1988, 2, 241.
  • 70
    • 43249101908 scopus 로고    scopus 로고
    • 2 in 2a is at ca. 215 ppm; therefore the parameters for this nucleus gained from simulation of this broad and mostly structureless signal are considered not to be very precise.
    • 2 in 2a is at ca. 215 ppm; therefore the parameters for this nucleus gained from simulation of this broad and mostly structureless signal are considered not to be very precise.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.