Mechanism of silver-promoted ligand metathesis in square-planar complexes of d8 ions. Kinetics of formation and molecular structures of a trinuclear intermediate [(Me)(N-N)Pt(μ-Cl)Ag(μ-Cl)Pt(N-N)(Me)]+ and its dinuclear evolution product [(Me)(N-N)Pt(μ-Cl)Pt(N-N)(Me)]+ (N-N = ArN=C(Me)C(Me)=NAr, Ar = 2,6-(i-Pr)2C6H3)

Inorganic Chemistry

Volumn 41, Issue 10, 2002, Pages 2672-2677

  Albano, Vincenzo G ^a   Di Serio, Martino ^b   Monari, Magda ^a   Orabona, Ida ^b   Panunzi, Achille ^b   Ruffo, Francesco ^b  

^a UNIVERSITY OF BOLOGNA   (Italy)

^b UNIVERSITY OF NAPLES FEDERICO II   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; CATION; CHELATE; CHLORIDE; ION; LIGAND; PLATINUM COMPLEX; SILVER CHLORIDE; SILVER DERIVATIVE; SOLVENT;

ACIDITY; ARTICLE; ATOM; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; X RAY DIFFRACTION;

EID: 0037140686     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic011059p     Document Type: Article

References (20)